bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I) | 74558-90-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I)
• 英文别名: bis(triphenylphosphine)iminium[Au(pentafluorophenyl)Cl]；PPN[AuCl(C6F5)]；bis(triphenyl-λ5-phosphanylidene)azanium;gold(1+);1,2,3,4,5-pentafluorobenzene-6-ide;chloride
• CAS: 74558-90-0
• 化学式: C₆AuClF₅*C₃₆H₃₀NP₂
• 分子量: 938.066
• InChiKey: HPHFSAHZWUSYQV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I) 在 thallium acetylacetonate 、 KOH 作用下， 以 二氯甲烷 、 丙酮 为溶剂， 生成
  参考文献：
  名称：

  A Novel Type of Alkynylgold(I) Complex. Crystal and Molecular Structures of PPN[Au(Ar)(C⋮CH)] [Ar = C₆F₅, C₆H₂(NO₂)₃-2,4,6]

  摘要：

  Complexes of the type PPN[Au(acac)(Ar)] [PPN = (Ph3P)(2)N, acac = acetylacetonate], obtained in solution from Tl(acac) and the corresponding PPN[Au(Ar)Cl] derivatives after removal of TlCl, react in situ with ethyne to give a new type of ethynylgold(I) complex, PPN[Au(Ar)(C drop CH)] [Ar = C6F5 (1), C6H4NO2-2 (2), C6H2(NO2)(3)-2,4,6(3)]. The crystal structures of 1 and 3 have been determined.

  DOI：

  10.1021/om9910322
• 作为产物：
  描述：

  pentafluorophenyl(tetrahydrothiophene)gold(I) 、 双(三苯基正膦基)氯化铵 以 丙酮 为溶剂， 以79%的产率得到bis(triphenylphosphane)iminium(pentafluorophenyl)chlorogold(I)
  参考文献：
  名称：

  与S-配体配体的复合物。5. †第一（氢硫基）-和阴离子亚硫基有机金（I）配合物的合成。的（ET晶体和分子结构4 N）2 [{的Au（C 6 ˚F 5）} 3（μ 3 -S）]·0.5MeC（O）的Et

  摘要：

  配合物Q [Au（R）Cl]在二乙胺的存在下与H 2 S反应，得到相应的有机（氢硫基）金（I）配合物Q [Au（R）（SH）] [R = C 6 F 5， Q = Ph 3 P N PPh 3 = PNP，Bu 4 N; Q ＝ PNP，R ＝ C 6 H 4 NO 2 -2，C 6 H 2（NO 2）3 -2,4,6]。在相同的反应条件中，Me 4 N [金（C 6 ˚F 5）氯]给出桥接有机（μ 3 -sulfido）金（I）络合物（ME 4 N）2[{的Au（C 6 ˚F 5）} 3（μ 3 -S）]，而的Et 4 N [金（C 6 ˚F 5）氯]给出的Et 4 N [金（C 6 ˚F 5）SH]或（ET 4 N）2 [{的Au（C 6 ˚F 5）} 3（μ 3 -S）]取决于后处理程序。的的Et的晶体结构4 N [{的Au（C 6 ˚F 5）} 3（μ 3-S）]·0.5MeC（O）Et已确定。Au···Au触头为3

  DOI：

  10.1021/om970106b

文献信息

• Synthesis and properties of alkynethiolate gold(i) complexes
  作者：Nora Lardiés、Inocencio Romeo、Elena Cerrada、Mariano Laguna、Peter J. Skabara

  DOI：10.1039/b708966j

  日期：——

  A series of alkynethiolate gold(I) derivatives have been synthesised by the cleavage of 4-monosubstituted 1,2,3-thiadiazoles in the presence of strong bases. The syntheses of the 1,2,3-thiadiazoles with p-cyanophenyl, p-tolyl, 2-thienyl, 3-thienyl and 9,9-dimethylfluoren-2-yl fragments are also described. All the complexes have been characterised by spectroscopic techniques and the complexes [Au(p-CH3–C6H4–CC–S)PPh3], [Au(3-C4H3S–CC–S)PPh3] and PPN[Au(p-CH3–C6H4–CC–S)(C6F5)] by X-ray analysis. The electrochemically polymerizable mononuclear bis(alkynethiolate) gold(I) complex PPN[Au(3-C4H3S–CC–S)2] is also described, including its electropolymerization and electrochemical properties.

  一系列炔硫醇合金(I)衍生物通过在强碱存在下裂解4-单取代的1,2,3-噻二唑合成得到。本文还描述了具有对氰苯基、对甲苯基、2-噻吩基、3-噻吩基和9,9-二甲基芴-2-基片段的1,2,3-噻二唑的合成方法。所有络合物均通过光谱技术进行了表征，并通过X射线分析对络合物[Au(p-CH3–C6H4–CC–S)PPh3]、[Au(3-C4H3S–CC–S)PPh3]和PPN[Au(p- – –CC–S)(C6F5)]进行了结构解析。本文还描述了电化学可聚合的单核双(炔硫醇合)金(I)络合物PPN[Au(3- –CC–S)2]，包括其电聚合过程和电化学性质。
• Bis(1,2,3‐thiadiazole)s as Precursors in the Synthesis of Bis(alkynethiolate)gold(I) Derivatives
  作者：Elena Cerrada、Mariano Laguna、Nora Lardíes

  DOI：10.1002/ejic.200800861

  日期：2009.1

  the general formula [Au2(S–C≡C–spacer–C≡C–S)L2] (L = monophosphanes; spacer = none, 1,4-C6H4, 1,3-C6H4, 2,7-C15H12 and 3,5-C7H7N). The dinuclear structure was confirmed by X-ray diffraction studies of the complexes (PPN)2[Au2(S–C≡C–C≡C–S)(C6F5)2] and [Au23,5-(S–C≡C)2–C7H7N}(PPh3)2] PPN = bis(triphenylphosphane)iminium}. The use of diphosphanes gives complexes with higher nuclearity and cyclic structures

  双（1,2,3-噻二唑）在强碱存在下的原位裂解得到双（炔硫醇），其提供双（炔硫醇）金（I）衍生物，通式为 [Au2(S–C ≡C–spacer–C≡C–S)L2]（L = 单膦；spacer = 无、1,4-C6H4、1,3- 、2,7-C15H12 和 3,5-C7H7N）。双核结构通过配合物 (PPN)2[Au2(S–C≡C–C≡C–S)(C6F5)2] 和 [Au23,5-(S–C ≡C)2– }(PPh3)2] PPN = 双(三苯基膦)亚胺}。双膦的使用产生具有更高核数和环状结构的复合物。（© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009）
• Heteroleptic gold complexes with 4,5-diselenolate-1,3-dithiole-2-thione (C₃C₃Se₂^2-, dsit)
  作者：Elena Cerrada、Mariano Laguna

  DOI：10.1139/v98-101

  日期：1998.7.1

  The reaction of (NBu₄)₂[Zn(dsit)₂] (dsit = 4,5-diselenolate-1,3-dithiole-2-thione) with AuClL in a 1:4 ratio leads to [Au₂(dsit)L₂] (L = PPh₃ (1), PPh₂Me (2)), transferring the diselenolate group. Complex 2 reacts further with equimolar amounts of [Au(OClO₃)L], affording the trinuclear complex [Au₃(dsit)(PPh₂Me)₃]ClO₄ (3). When the reaction of (NBu₄)₂[Zn(dsit)₂] with [Au₂Cl₂(P-P)] was carried out in a 1:2 ratio, complexes [Au₂(dsit)(P-P)]_n (P-P = dppe (1,2-bis(diphenylphosphine)ethane), n = 1 (4); P-P = dppm (bis(diphenylphosphine)methane), n = 2 (5)) are obtained. Anionic derivatives such as (NBu₄)[Au(dsit)₂] (6) could be obtained by reaction of the zinc complex with (NBu₄)[AuBr₄] in a 1:1 ratio while other gold complexes require a tin complex as ligand transfer. So [Sn(dsit)Me₂] (7), obtained from the zinc complex and [SnCl₂Me₂], reacts with PPN[Au(C₆F₅)Cl] (PPN = bis(triphenylphosphine)iminium) or [AuBr₂(S₂CNR₂)] affording [Au(dsit)(S₂CNR₂)] (R = Me (8); R = Bz (9)) or (PPN)₂[Au₂(dsit)(C₆F₅)₂] (10), respectively. Electrochemical oxidation of 6 gives (NBu₄)_0.4[Au(dsit)₂] (11) and the reaction with (TTF)₃(BF₄)₂ (TTF = tetrathiafulvalene) affords (TTF)[Au(dsit)₂] (12). Electrical conductivities of these complexes at room temperature in compacted pellets are 3 × 10^-8 (11) and 5 × 10^-3 (12) S cm^-1.Key words: diselenolate, dsit, gold complexes, tin complexes.

  使用1:4比例的AuClL与(NBu4)2[Zn(dsit)2] (dsit = 4,5-二硒代-1,3-二硫代-2-硫醇基)反应，可以得到[Au2(dsit)L2] (L = PPh3 (1), PPh2Me (2))，转移了二硒代基团。复合物2进一步与等量的[Au(OClO3)L]反应，得到三核复合物[Au3(dsit)(PPh2Me)3]ClO4 (3)。当(NBu4)2[Zn(dsit)2]与[Au2CL2(P-P)]在1:2比例下反应，可以得到复合物[Au2(dsit)(P-P)]n (P-P = dppe (1,2-双苯基膦乙烷)，n = 1 (4); P-P = dppm (双苯基膦甲烷)，n = 2 (5))。通过(NBu4)2[Zn(dsit)2]与(NBu4)[AuBr4]在1:1比例下反应，可以得到阴离子衍生物(NBu4)[Au(dsit)2] (6)，而其他金复合物需要锡配合物作为配体转移。因此，从锌配合物和[SnCL2Me2]得到的[Sn(dsit)Me2] (7)可以与PPN[Au(C6F5)Cl] (PPN = 双三苯基膦亚胺)或[AuBr2(S2CNR2)]反应，分别得到[Au(dsit)(S2CNR2)] (R = Me (8); R = Bz (9))或(PPN)2[Au2(dsit)( )2] (10)。复合物6的电化学氧化得到(NBu4)0.4[Au(dsit)2] (11)，与(TTF)3(BF4)2 (TTF = 四硫富瓦烯)反应可以得到(TTF)[Au(dsit)2] (12)。这些复合物在室温下压缩成颗粒后的电导率为3×10-8 (11)和5×10-3 S cm-1 (12)。关键词：二硒代基，dsit，金复合物，锡复合物。
• Bimetallic gold—silver pentachlorophenyl complexes
  作者：Rafael Uson、Antonio Laguna、Mariano Laguna、Blanca R. Manzano、Amado Tapia

  DOI：10.1016/s0020-1693(00)87648-3

  日期：1985.7
• Synthesis and Reactivity of Heteroleptic Complexes of Gold with 2-Thioxo-1,3-dithiole-4,5-dithiolate (dmit). X-ray Structure of [Au₂(μ-dmit)(PPh₃)₂], (NBu₄)[Au(dmit)(PPh₃)], and (PPN)[Au(dmit)(C₆F₅)₂]
  作者：Elena Cerrada、Peter G. Jones、Antonio Laguna、Mariano Laguna

  DOI：10.1021/ic950893+

  日期：1996.1.1

  The reactions of Na(2)dmit (dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate) with AuClL in 1:2 ratios lead to [Au-2(dmit)L(2)] [L = PPh(3) (1), PPh(2)Me (2), PPhMe(2) (3), PMe(3) (4), CH(2)PPh(3) (5), CH(2)PPh(2)Me (6), CH(2)PPhMe(2) (7)]. Complexes 1, 2, and 5 react further with equimolecular amounts of [AuL(tht)]ClO4 (tht = tetrahydrothiophene), affording trinuclear complexes [Au-3(dmit)L(3)]ClO4 (8-10). When the reactions of Na(2)dmit with AuClL are carried out in 1:1 ratios and in the presence of NBu(4)Br, mononuclear tricoordinated gold(I) complexes NBu(4)[Au(dmit)L] [L = PPh(3) (11), PPh(2)Me (12), PMe(3) (13)] are obtained. Other anionic derivatives such as (PPN)(2)[Au-2(dmit)X(2)] [X = C6F5 (14), Cl (15a) Br (15b)] can be obtained either by reaction of Na(2)dmit with Q[Au(C6F5)X] in 1:2 ratio or by addition of (PPN)X to the recently reported [Au-2(dmit)(AsPh(3))]. Oxidative reactions of 11, 12, and 14 or 15b with excess (TTF)(3)(BF4)(2) afford (TTF)(2)[Au(dmit)(2)] (16), (TTF)[Au-2(dmit)(C6F5)(2)] (17), and (TTF)(3)[Au-2(dmit)Br-2] (18), respectively. Reaction of complex 14 with TCNQ gives the anionic gold(III) complex [Au(dmit)(C6F5)(2)](-) (19). Electrical conductivities of these complexes at room temperature in compacted pellets are 2 x 10(-3) (16), 7 x 10(-5) (17), and 2 x 10(-2) (18) S . cm(-1). Electrocrystallization of 1 and 11 affords [Au-2(dmit)(2)(PPh(3))] (20) and the known NBu(4)[Au(dmit)(2)], respectively. X-ray structure determinations were performed for complexes 1, 11, and 19b.