[silver(I)(2-(3'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)](ClO4)*H2O | 870082-71-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [silver(I)(2-(3'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)](ClO4)*H2O
• 英文别名: [Ag(NIT3Py)3]ClO4*H2O
• CAS: 870082-71-6
• 化学式: C₃₆H₄₈AgN₉O₆*ClO₄*H₂O
• 分子量: 928.168
• InChiKey: SJWUZOMQPVPXKP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水 、 silver perchlorate 、 2-(pyrid-3-yl)-4,4,5,5-tetramethylimidazolidine-3-oxide-1-oxyl 以 甲醇 为溶剂， 生成 [silver(I)(2-(3'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)](ClO4)*H2O
  参考文献：
  名称：

  A Novel Ferromagnetic Coupling Complex with Silver Ion and Nitronyl Nitroxide

  摘要：

  A novel complex [Ag(NIT3Py)(3)]center dot(H2O)(ClO4) has been synthesized and structurally characterized by X-ray diffraction methods. It crystallizes in the rhombohedral space group R-3. The structure consists of Ag(NIT3Py)(3)(+) moiety, one water molecule, and one perchloric ion. The Ag(I) ion is in a trigonal planar environment, which is formed by three nitrogen atoms from three NIT3Py. Variable temperature magnetic susceptibility measurements reveal the occurrence of weak ferromagnetic interactions in the compound.

  DOI：

  10.1080/15533170802371414