2,2,2-Trichloroethyldithioethyl-S-ethylthiolcarbonate | 34764-33-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代缩醛
• 英文名称: 2,2,2-Trichloroethyldithioethyl-S-ethylthiolcarbonate
• 英文别名: 2,2,2-Trichlorethyldithioethyl-S-ethylthiolcarbonat
• CAS: 34764-33-5
• 化学式: C₇H₁₁Cl₃O₂S₃
• 分子量: 329.72
• InChiKey: UNZLSSQOJIJEOG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.63
• 重原子数：
  15.0
• 可旋转键数：
  6.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  26.3
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  2,2,2-Trichlorethyldithioethyl-chlorformiat 、 乙硫醇 在 三乙胺 作用下， 生成 2,2,2-Trichloroethyldithioethyl-S-ethylthiolcarbonate
  参考文献：
  名称：

  Carbonates and thio carbonates of polyhalodisulfide alcohols

  摘要：

  公开号：

  US03629312A1

文献信息

• Polyhalo ethyl-and polyhalo vinyl-dithioethyl carbonates and thio carbonates
  申请人：BOYCHEM CORPORATION

  公开号：US03683000A1

  公开（公告）日：1972-08-08

  Compounds are prepared having one of the formulas WHERE A is selected from the group consisting of di to tetrahaloethyl and di to trihalovinyl; B is selected from the group consisting of hydrogen and -CH2OH; D is selected from the group consisting of hydrogen and E is selected from the group consisting of hydrogen and G is selected from the group consisting of hydrogen and N IS 0 OR 1, X is selected from the group consisting of oxygen and sulfur except that when n is 0 in formula (2) X must be oxygen; Q is halogen; R1 is selected from the group consisting of alkyl, phenyl, lower alkyl phenyl, halo lower alkyl, halophenyl, naphthyl, lower alkyl naphthyl and lower alkyl halophenyl; R2 and R3 individually are the same as R1 or hydrogen with the proviso that not more than one of R2 and R3 is hydrogen and collectively together with the adjacent nitrogen atom form a five to six membered heterocyclic ring having up to 1 oxygen atom therein; R4 is R1 or OR PHENYL ETHYLENE OR HALOPHENOXYMETHYL HAVING UP TO 3 HALOGENS AND UP TO 1 METHYL GROUP ON THE AROMATIC RING; K is selected from the group consisting of J is selected from the group consisting of hydrogen and ASSCH2CH2-; m is an integer from 0 to 2 inclusive, and all halogen atoms in the compounds have an atomic weight of 35 to 80.

  化合物制备的公式之一为：其中A选自二至四卤乙基和二至三卤乙烯基组成的群体；B选自氢和-CH2OH组成的群体；D选自氢；E选自氢；G选自氢；N为0或1；X选自氧和硫，但在公式（2）中当n为0时，X必须为氧；Q为卤素；R1选自烷基、苯基、低烷基苯基、卤代低烷基、卤代苯基、萘基、低烷基萘基和低烷基卤代苯基组成的群体；R2和R3分别与R1相同或为氢，但R2和R3中最多只有一个为氢，且与相邻氮原子共同形成含有最多1个氧原子的五至六元杂环环；R4为R1或苯基乙烯基或卤代苯氧基甲基，其芳香环上最多有3个卤原子和1个甲基基团；K选自J；J选自氢和ASSCH2CH2-；m为0至2的整数，化合物中的所有卤素原子的原子量为35至80。
• US3784563
  申请人：——

  公开号：——

  公开（公告）日：——
• US3760002
  申请人：——

  公开号：——

  公开（公告）日：——
• Polyhalo disulfide alcohol derivatives
  申请人：BAYCHEM CORPORATION

  公开号：US03652653A1

  公开（公告）日：1972-03-28
• Alkyl and aryl esters of polyhalo-dithio alcohols
  申请人：CARL D EMERSON

  公开号：US03641109A1

  公开（公告）日：1972-02-08