9-((tetrahydrofuran-3-yl)methyl)-4-nitro-8-oxa-10, 11-dihydroimidazo-[2,3-a]-bicyclo-[3,2,1]-oct-3-ene | 1310352-18-1

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: 9-((tetrahydrofuran-3-yl)methyl)-4-nitro-8-oxa-10, 11-dihydroimidazo-[2,3-a]-bicyclo-[3,2,1]-oct-3-ene
• 英文别名: (1S,8R)-7-nitro-5-(oxolan-3-ylmethyl)-11-oxa-2,5-diazatricyclo[6.2.1.02,6]undec-6-ene
• CAS: 1310352-18-1
• 化学式: C₁₃H₁₉N₃O₄
• 分子量: 281.312
• InChiKey: KVVAOCPPLXAVDH-ZOCYIJKUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  70.8
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• DIVALENT AND OXABRIDGED HETEROCYCLIC NEONICOTINOID COMPOUNDS AND PREPARATION METHODS THEREOF
  申请人：Qian Xuhong

  公开号：US20120245126A1

  公开（公告）日：2012-09-27

  Nitromethylene analogues of imidacloprid and divalent and oxabridged heterocyclic neonicotinoid compounds constructed by dialdehydes, preparation methods and uses thereof are disclosed. Compounds represented by formula (A) or (B), their optical isomers or agrochemically acceptable salts are provided. Agrochemical compositions comprising the said compounds, their optical isomers or agrochemically acceptable salts, the uses of the said agrochemical compositions and the preparation methods of the said compounds, their optical isomers or agrochemically acceptable salts are also disclosed. The compounds and their derivatives have high insecticidal activities to several farming and forestry pests including homoptera and lepidoptera pests, such as aphis , fulgorid, whitefly, leafhopper, common thrips, cotton bollworm, cabbage caterpillar, cabbage moth, cotton leafworm and armyworm.

  本文揭示了由二醛构建的硝基咪虫啉类和二价及氧桥杂环新烟碱类化合物的亚硝基甲烯类似物，其制备方法和用途。提供了由式（A）或（B）表示的化合物及其光学异构体或农业化学上可接受的盐。还揭示了包含所述化合物、其光学异构体或农业化学上可接受的盐的农药组合物，所述农药组合物的用途以及所述化合物、其光学异构体或农业化学上可接受的盐的制备方法。这些化合物及其衍生物对多种农林害虫具有高效的杀虫活性，包括同翅目和鳞翅目害虫，如蚜虫、叶蝉、白粉虱、跳小蜂、普通蓟马、棉铃虫、菜青虫、小菜蛾、棉叶虫和军农虫。
• US8809319B2
  申请人：——

  公开号：US8809319B2

  公开（公告）日：2014-08-19