dioxomolybdenum(2+);N'-[1-(2-fluorophenyl)ethylideneamino]carbamimidothioate | 191614-50-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dioxomolybdenum(2+);N'-[1-(2-fluorophenyl)ethylideneamino]carbamimidothioate
• CAS: 191614-50-3
• 化学式: C₁₈H₁₈F₂MoN₆O₂S₂
• 分子量: 548.449
• InChiKey: KPOSABVJHWDGQO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.58
• 重原子数：
  31
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  138
• 氢给体数：
  2
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  bis(acetylacetonato)dioxidomolybdenum(VI) 、 2-[1-(2-fluorophenyl)ethylidene]hydrazinecarbothioamide 以 甲醇 为溶剂， 以75%的产率得到dioxomolybdenum(2+);N'-[1-(2-fluorophenyl)ethylideneamino]carbamimidothioate
  参考文献：
  名称：

  A New Series of Biologically Potentcis-Dioxomolybdenum(VI) Complexes of Fluoroimines

  摘要：

  The modern physico-chemical, spectroscopic and biochemical methods have proved an important tool to elucidate the constitution of reactive transition metal compounds. This article presents a brief account of the synthesis and stereochemistry of dioxomolybdenum(VI) complexes of fluoroimines. The mononuclear complexes were obtained by bimolar reactions of dioxobis(2,4-pentanediona-to-O,O')molybdenum(VI) with the monobasic bidentate fluoroimines containing N boolean AND S and N boolean AND O as the binding sites. Based on chemical analyses, IR and NMR spectra, conductance measurements and molecular weight determinations an octahedral geometry has been assigned to the newly synthesized products. The possibility of potential uses of these complexes as fungicides and bactericides, studied in vitro are also discussed.

  DOI：

  10.1080/00945719708000225