1,6-dihydro-11,11-dimethyl-1,6,11-trisilabicyclo[4.4.1]undecane | 896744-32-4

• 分子结构分类: 有机化合物
• 英文名称: 1,6-dihydro-11,11-dimethyl-1,6,11-trisilabicyclo[4.4.1]undecane
• CAS: 896744-32-4
• 化学式: C₁₀H₂₄Si₃
• 分子量: 228.557
• InChiKey: LRIMMLQGVCHGQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.89
• 重原子数：
  13.0
• 可旋转键数：
  0.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  1,6-dihydro-11,11-dimethyl-1,6,11-trisilabicyclo[4.4.1]undecane 在 四氯化碳 作用下， 反应 96.0h， 生成 1,6-dichloro-11,11-dimethyl-1,6,11-trisilabicyclo[4.4.1]undecane
  参考文献：
  名称：

  all-anti-Octasilane:  Conformation Control of Silicon Chains Using the Bicyclic Trisilane as a Building Block

  摘要：

  The perfect all-anti-octasilane composed of two bicyclic trisilane units with trimethylsilyl groups at the termini has been synthesized. Its X-ray crystal structure and spectroscopic data demonstrate the effective sigma-delocalization over the silicon framework, which is a definitive difference from the unconstrained n-Si8Me18.

  DOI：

  10.1021/ja0616231
• 作为产物：
  描述：

  (Z)-1,6-diisopropoxy-11,11-dimethyl-1,6,11-trisilabicyclo[4.4.1]undec-3-ene 在 RhCl(PPh₃)3 氢气 、 二异丁基氢化铝 作用下， 以 甲苯 为溶剂， 反应 61.5h， 生成 1,6-dihydro-11,11-dimethyl-1,6,11-trisilabicyclo[4.4.1]undecane
  参考文献：
  名称：

  all-anti-Octasilane:  Conformation Control of Silicon Chains Using the Bicyclic Trisilane as a Building Block

  摘要：

  The perfect all-anti-octasilane composed of two bicyclic trisilane units with trimethylsilyl groups at the termini has been synthesized. Its X-ray crystal structure and spectroscopic data demonstrate the effective sigma-delocalization over the silicon framework, which is a definitive difference from the unconstrained n-Si8Me18.

  DOI：

  10.1021/ja0616231