strontium monoiodide | 14696-99-2

• 分子结构分类: 无机化合物 - 均质非金属化合物
• 英文名称: strontium monoiodide
• CAS: 14696-99-2
• 化学式: ISr
• 分子量: 214.524
• InChiKey: XGFYTJDYXSABRS-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  氢化锶 在 碘甲烷 作用下， 以 gaseous matrix 为溶剂， 生成 strontium monoiodide
  参考文献：
  名称：

  测量Sr + CH 3 I→SrI + CH 3反应的横截面平移能量依赖性，范围为0.1 – 1.0 eV

  摘要：

  Sr + CH 3 I→SrI + CH 3反应相对截面的碰撞能量依赖性通过交叉分子束技术测量，范围为0.1 – 1.0 eV。喷出的Sr光束与脉冲CH 3 I光束成直角相交。在193 nm激光单光子电离后，使用飞行时间质谱在散射区中检测到SrI产物。（σ横截面- [R ）该反应的随急剧降低Ë Ť直至接近0.35电子伏特达到明显最小值。该最小值后，σ [R逐渐增加而增加ë Ť。与K + CH 3相反I反应（ME Gersh和RB Bernstein，J.Chem.Phys.55（1971）4661； 56（1972）6131），未观察到该反应的明显最大值。如果存在这样的最大值，则必须在0.1 eV以下发生。

  DOI：

  10.1016/0009-2614(91)90244-4

文献信息

• Steric effects in chemiluminescent reactions of metastable Ca∗, Sr∗ atoms with isomeric propyl halides
  作者：B. Pranszke、P. Kierzkowski、A. Kowalski

  DOI：10.1016/s0009-2614(99)00676-4

  日期：1999.8

  Reactions of metastable alkaline earth atoms with normal and branched propyl halides were studied in a beam-gas arrangement. Chemiluminescence spectra of alkaline earth monohalides were observed for calcium and strontium reactions. Some differences in the CaX () branching ratio were found with isomeric variation of the targets. Total collision cross-sections for Mg∗ and Ca∗ reactions are independent

  在束流-气体装置中研究了亚稳碱土原子与正卤和支链丙基卤的反应。观察到钙和锶反应的碱土金属卤化物的化学发光光谱。发现CaX（）支化比率存在一些差异，这与靶标的异构体变异有关。Mg ＊和Ca ＊反应的总碰撞截面与异构体取代无关。对于锶，异丙基碘的值比正常丙碘靶的值高50％。发现钙与丙碘化物和丙氯的反应在化学发光横截面上存在差异。
• Translational energy dependence of the reaction cross section: Reactions of Sr+CH₃I, CD₃I, and CH₃Br
  作者：Qi‐Xun Xu、R. Scott Mackay、F. Javier Aoiz、Richard B. Bernstein

  DOI：10.1063/1.462090

  日期：1992.2

  The excitation functions for the crossed beam reactions of Sr+CH3I, CD3I, and CH3Br have been investigated over the collisional energy (ET) range 0.1 to ∼1.0 eV. A highly sensitive single photon ionization technique has been developed to detect the reaction products (SrI and SrBr). The integrated total reaction cross sections (σR) exhibit very different behavior in reactions with CH3I vs CH3Br. In the reaction of Sr+CH3I, σR decreases sharply with increasing ET to a minimum near 0.35±0.05 eV and then gradually increases with increasing ET. In the isotopically substituted reactant, CH3I, no difference in the excitation function is seen within the resolution of the experiment. However, for the reaction Sr+CH3Br, σR exhibits a threshold around 0.12±0.05 eV and gradually increases with increasing ET. The present data for the Sr reactions with CH3I and CH3Br are compared with analogous alkali metal reactions and with several theoretical models.