2-Methoxyethyl-2-methyl-1-propenyl-ether | 30413-37-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-Methoxyethyl-2-methyl-1-propenyl-ether
• 英文别名: 2-Methoxyethyl-2-methylpropenylether；1-(2-methoxy-ethoxy)-2-methyl-propene；1-(2-Methoxyethoxy)-2-methylprop-1-ene
• CAS: 30413-37-7
• 化学式: C₇H₁₄O₂
• 分子量: 130.187
• InChiKey: SJWUXZHHNZBQOQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  6-(1-甲基乙基)-2,5,7,10-四氧杂十一烷 在 对甲苯磺酸 作用下， 生成 2-Methoxyethyl-2-methyl-1-propenyl-ether
  参考文献：
  名称：

  邻苯二甲醛与各种大体积烯醇醚的活性和交替阳离子共聚：阐明可聚合单体的“极限”

  摘要：

  各种大体积的烯醇醚的阳离子共聚，它们一直难以均聚和/或共聚，表明当o-苯二甲醛（OPA）用作共聚单体。以脂肪醛和脂肪醇为原料，合成了一系列在β-碳上具有不同取代基的烯醇醚。系统研究了烯醇醚结构与共聚行为的关系。结果，发现在 β-碳上具有一个或两个甲基和/或伯烷基的单体与 OPA 进行交替共聚。此外，烯醇醚和OPA的活性阳离子共聚在适当的聚合条件下产生交替共聚物。为了阐明可聚合单体的限制，非常庞大的烯醇醚如 β- t的共聚还检查了具有 OPA 的 -丁基或降冰片亚基型单体。发现 OPA 即使与如此庞大的单体也可共聚，这表明 OPA 衍生的增长碳正离子具有较小的空间位阻的独特反应性是成功共聚的关键因素。

  DOI：

  10.1021/acs.macromol.1c02398

文献信息

• PROCESS FOR PRODUCING ETHER COMPOUND
  申请人：Kyowa Yuka Co., Ltd.

  公开号：EP1415968A1

  公开（公告）日：2004-05-06

  The present invention provides the following process for produci ng and the like, which enables the production of an ether compound, which is useful for chemical amplification type resist compositions, synthetic intermediates of pharmaceuticals, paints, or the like, with less side reaction and in high yield. A process for producing an ether compound having a group represented by the general formula (II) wherein R1, R2 and R3 may be the same or different, and represent substituted or unsubstituted alkyl, substituted or unsubstituted aryl or substituted or unsubstituted aralkyl, or R1 and R2 form cycloalkyl together with an adjacent carbon atom,    which comprises allowing a compound having a hydroxyl group (including a carboxyl group) to react with an alkenyl ether represented by the general formula (I) wherein R1, R2 and R3 have the same significances as defined above, respectively.

  本发明提供了以下用于生产等的过程，该过程能够生产醚化合物，该化合物对于化学放大型抗蚀组合物、药物合成中间体、涂料等具有用途，且副反应较少且产率高。一种生产具有由通式（II）表示的基团的醚化合物的方法，其中R1、R2和R3可以相同也可以不同，并表示取代或未取代的烷基、取代或未取代的芳基或取代或未取代的芳基烷基，或者R1和R2与相邻碳原子一起形成环烷基，包括允许具有羟基（包括羧基）的化合物与由通式（I）表示的烯基醚发生反应，其中R1、R2和R3分别具有上述定义的相同含义。
• Process for producing ether compound
  申请人：Shimizu Ikuo

  公开号：US20060074262A1

  公开（公告）日：2006-04-06

  The present invention provides the following process for producing and the like, which enables the production of an ether compound, which is useful for chemical amplification type resist compositions, synthetic intermediates of pharmaceuticals, paints, or the like, with less side reaction and in high yield. A process for producing an ether compound having a group represented by the general formula (II) wherein R 1 , R 2 and R 3 may be the same or different, and represent substituted or unsubstituted alkyl, substituted or unsubstituted aryl or substituted or unsubstituted aralkyl, or R 1 and R 2 form cycloalkyl together with an adjacent carbon atom, which comprises allowing a compound having a hydroxyl group (including a carboxyl group) to react with an alkenyl ether represented by the general formula (I) wherein R 1 , R 2 and R 3 have the same significances as defined above respectively.

  本发明提供了以下用于生产等的过程，使得能够以较少的副反应和高收率生产对化学放大型抗蚀剂组合物、制药中间体、油漆或类似物有用的醚化合物。一种生产醚化合物的过程，该醚化合物具有由通式（II）表示的基团，其中R1、R2和R3可以相同或不同，并且分别表示取代或未取代的烷基、取代或未取代的芳基或取代或未取代的芳基烷基，或者R1和R2与相邻的碳原子一起形成环状烷基，该过程包括使具有羟基（包括羧基）的化合物与由通式（I）表示的烯基醚反应，其中R1、R2和R3分别具有上述定义的相同意义。
• POSITIVE RESIN COMPOSITION OF NEAR-INFRARED-RAY ACTIVATION TYPE
  申请人：KANSAI PAINT CO., LTD.

  公开号：EP1788432A1

  公开（公告）日：2007-05-23

  A near infrared ray activation type positive resist composition comprising (A) a vinyl-based polymer having a monomer unit having an alkali-soluble group blocked by an ether having an alkenyl group next to an ether oxygen, (B) a photothermal converting substance generating heat by a light in the near infrared region, (C) a thermal acid generator generating an acid by heat, can provide a near infrared ray activation type positive resist composition which can be subjected to an exposure treatment in a complete bright room such as under a white light and the like, gives desired sensitivity and resolution, and of which baking treatment conditions can be relaxed or a baking treatment can be omitted, and a pattern formation method using the same.

  一种近红外射线活化型正抗蚀剂组合物，包括 (A) 乙烯基聚合物，其单体单元具有碱溶性基团，该基团被醚封住，醚氧旁边具有烯基、 (B) 通过近红外区域的光产生热量的光热转换物质、 (C) 通过热量产生酸的热酸发生器、 本发明可提供一种近红外射线活化型正抗蚀剂组合物，该组合物可在完全明亮的室内（如在白光等下）进行曝光处理，可获得所需的灵敏度和分辨率，其烘烤处理条件可放宽或省略烘烤处理，还可提供使用该组合物的图案形成方法。
• Near Infrared Ray Activation Type Positive Resin Composition
  申请人：Imai Genji

  公开号：US20070259279A1

  公开（公告）日：2007-11-08

  A near infrared ray activation type positive resist composition comprising (A) a vinyl-based polymer having a monomer unit having an alkali-soluble group blocked by an ether having an alkenyl group next to an ether oxygen, (B) a photothermal converting substance generating heat by a light in the near infrared region, (C) a thermal acid generator generating an acid by heat, can provide a near infrared ray activation type positive resist composition which can be subjected to an exposure treatment in a complete bright room such as under a white light and the like, gives desired sensitivity and resolution, and of which baking treatment conditions can be relaxed or a baking treatment can be omitted, and a pattern formation method using the same.
• US7015363B2
  申请人：——

  公开号：US7015363B2

  公开（公告）日：2006-03-21