Ethanesulfonic acid ((1R,2R)-2-ethanesulfonylamino-cyclohexyl)-amide | 143585-45-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: Ethanesulfonic acid ((1R,2R)-2-ethanesulfonylamino-cyclohexyl)-amide
• CAS: 143585-45-9
• 化学式: C₁₀H₂₂N₂O₄S₂
• 分子量: 298.428
• InChiKey: KWKMANJWGVNDBV-NXEZZACHSA-N

反应信息

• 作为产物：
  描述：

  (1R,2R)-1,2-diaminocyclohexane 、 乙基磺酰氯 在 N,N-二异丙基乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 Ethanesulfonic acid ((1R,2R)-2-ethanesulfonylamino-cyclohexyl)-amide
  参考文献：
  名称：

  A catalytic enantioselective reaction using a C2-symmetric disulfonamide as a chiral ligand: Alkylation of aldehydes catalyzed by disulfonamide-Ti(O-i-Pr)4-Dialkyl zinc system

  摘要：

  DOI：

  10.1016/0040-4020(92)80020-g

文献信息

• Catalytic enantioselective cyclopropanation with bis(halomethyl)zinc reagents. II. The effect of promoter structure on selectivity
  作者：Scott E. Denmark、Beritte L. Christenson、Stephen P. O'Connor

  DOI：10.1016/0040-4039(95)00259-f

  日期：1995.3

  The catalytic, enantioselective cyclopropanation of cinnamyl alcohol has been accomplished with bis(iodomethyl)zinc in the presence of chiral bis(sulfonamides) derived from cyclohexanediamine. An extensive survey of diamine and sulfonamide structure has revealed a marked sensitivity to the spatial relationship of the amine groups, but only a modest dependence on the sulfonamide residue.