| 192937-32-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 192937-32-9
• 化学式: C₃₉H₃₉BrCoN₅O₄
• 分子量: 780.667
• InChiKey: BCTKCNWLMDVTPD-AGMWPDPBSA-L

反应信息

• 作为产物：
  描述：

  1,6-二溴己烷 、 [Co(diphenylglyoximato)₂Cl(pyridine)] 在 sodium tetrahydroborate 作用下， 以 not given 为溶剂， 以9%的产率得到
  参考文献：
  名称：

  Organobridged dicobaloximes: Synthesis and NMR correlation

  摘要：

  Organobridged dicobaloximes of the type Py(L)(2)Co-III-(CH2)(n)-Co-III(L)(2)Py [L = dmgH(-) and dpgH(-), n = 3,4,5,6 and 10] are synthesized by the reaction of Co-l(L)(2)Py with the corresponding alkyl dihalides. A mixture of haloalkylcobaloximes and the dicobaloxime is formed in each reaction. The purification procedure for the dicobaloxime is established. A comparison of 'cis influence' due to the equatorial ligands in the haloalkyl and the dicobaloximes by H-1 NMR reveals that the extent of the cis influence on the Co-CH2 resonance is more in the case of the dicobaloxime but it is nearly same for the P-alpha and the P-gamma resonances.

  DOI：

  10.1016/s0022-328x(96)06885-4