| 1374861-96-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• CAS: 1374861-96-7
• 化学式: C₂F₆NO₄S₂*C₂H₇NO*Li
• 分子量: 348.173
• InChiKey: AABVZKNOADSLHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.0
• 重原子数：
  20.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  128.63
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  C.I.酸性橙108 、 bis(trifluoromethane)sulfonimide lithium 反应 2.0h， 生成
  参考文献：
  名称：

  具有多齿阳离子配位的可调谐链烷醇胺基离子液体可高效捕获二氧化碳。

  摘要：

  一系列新型的基于烷醇胺的离子液体显示出通过拟氮杂冠状醚形式的烷醇胺和Li（+）离子之间的多齿阳离子配位，可高效高效地捕获CO（2）。

  DOI：

  10.1039/c2cc32365f

文献信息

• Effect of the Temperature and Coordination Atom on the Physicochemical Properties of Chelate-Based Ionic Liquids and Their Binary Mixtures with Water
  作者：Minming Shen、Siying Che、Yuyang Zhang、Jia Yao、Haoran Li

  DOI：10.1021/je5004065

  日期：2014.12.11

  Densities, viscosities, and conductivities of four chelate-based ionic liquids [Li(DOBA)][Tf2N], [Li(HDA)][Tf2N], [Li(DEA)][Tf2N], and [Li(EA)][Tf2N], and their binary mixtures with water were determined. Physical properties of [Li(DEA)][Tf2N], such as the thermal expansion coefficient of the ionic liquid, were calculated by empirical equations over a temperature range from 313.15 K to 333.15 K. The excess molar volume (VE) and viscosity deviations (Delta eta) were fitted by a Redlich-ister equation. The excess molar volumes show a negative deviation from that of the ideal solution and two different behaviors between water-rich and IL-rich regions. Most viscosity deviations show negative values, except for that of the binary mixture of [Li(DOBA)][Tf2N]/water. The effect of chelate state on the above physicochemical properties has been discussed. Furthermore, the Walden rule was used to evaluate the relationship of molar conductivity and dynamic viscosity of these ionic liquid solutions, which indicates all of them have good ionicity.