PtMe3(OC(Me)C(Me)NO)(2,2'-bipyridyl) | 165463-06-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: PtMe3(OC(Me)C(Me)NO)(2,2'-bipyridyl)
• CAS: 165463-06-9
• 化学式: C₁₇H₂₃N₃O₂Pt
• 分子量: 496.469
• InChiKey: PIVLEVOUPBGPRE-NMWKCBCISA-M

反应信息

• 作为产物：
  描述：

  在 2,2'-联吡啶 作用下， 以 苯 为溶剂， 以95%的产率得到PtMe3(OC(Me)C(Me)NO)(2,2'-bipyridyl)
  参考文献：
  名称：

  Complexes of trimethylplatinum(IV) with butane-2,3-dione monoxime

  摘要：

  The dimeric complex of butane-2,3-dione monoxime (Hbdm) with trimethylplatinum(IV), [{PtMe(3)(bdm)}(2)] 1, and its pyridine (py) and 2,2'-bipyridyl (bipy) adducts [PtMe(3)(bdm)(py)] and [PtMe(3)(bdm)(bipy)], show three different configurations for the ionised monoxime ligand. Dimer 1 forms a fluxional solvated monomer in co-ordinating solvents. Its solution-state stereodynamics in CD,OD have been measured by two-dimensional exchange NMR spectroscopy and a 'windscreen-wiper' mechanism proposed which is novel in trimethylplatinum(IV) chemistry.

  DOI：

  10.1039/dt9950001233