cis-[(CH3NH2)2Pt(1-ethylthiminato-N3)2] | 198560-02-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯啉
• 英文名称: cis-[(CH3NH2)2Pt(1-ethylthiminato-N3)2]
• CAS: 198560-02-0
• 化学式: C₁₆H₂₈N₆O₄Pt
• 分子量: 563.516
• InChiKey: QIRLJJCMUNGZEA-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  potassium tetrachloroplatinate(II) 、 cis-[(CH3NH2)2Pt(1-ethylthiminato-N3)2] 以 水 为溶剂， 以50%的产率得到cis-[(CH3NH2)2Pt(1-ethylthiminato)2PtCl2]
  参考文献：
  名称：

  +3 Oxidation state of platinum in dinuclear complexes with thymine nucleobases: structural and solution studies

  摘要：

  A series of diplatinum(III) complexes containing two bridging 1-methylthyminato (1-MeT) and 1-ethylthyminato (1-EtT) nucleobase ligands in a head-head orientation has been prepared and/or studied in solution. The compounds are of general composition [Xa(2)PtL(2)Pta(2)Y](n+) and [Xa(2)PtL(2)PtCl(2)Y](n+) with a = NH3 or CH3NH2, L = thymine nucleobase, and X, Y being axial ligands such as NO2, Cl-, H2O or no ligand at all. Full crystallographic details of two compounds and preliminary data of two additional representatives are given. Synthetic procedures are sometimes poorly reproducible as a consequence of ready substitution reactions of the axial ligands. X-ray crystallography is frequently the only reliable method in establishing the nature of X and Y ligands. The potential usefulness of radial distribution functions (RDFs) of atoms in powder samples for characterizing diplatinum(III) complexes is briefly discussed. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05710-1