2-adamantan-2-yl-thiophene | 14449-37-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 2-adamantan-2-yl-thiophene
• 英文别名: 2-<2-Adamantyl>-thiophen；2-(2-Adamantyl)-thiophen；2-(2-Adamantyl)thiophene
• CAS: 14449-37-7
• 化学式: C₁₄H₁₈S
• 分子量: 218.363
• InChiKey: XQGUIBGCVCBXKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-adamantan-2-yl-thiophene 在 镍 作用下， 以 乙醇 为溶剂， 生成 2-(n-butyl)adamantane
  参考文献：
  名称：

  Hoek,W. et al., Recueil des Travaux Chimiques des Pays-Bas, 1966, vol. 85, p. 1045 - 1053

  摘要：

  DOI：
• 作为产物：
  描述：

  2-溴噻吩 、 2-溴代金刚烷 在 锌 、 2-双环己基膦-2',6'-二甲氧基联苯 、 palladium diacetate 作用下， 以 四氢呋喃 为溶剂， 反应 26.0h， 以70%的产率得到2-adamantan-2-yl-thiophene
  参考文献：
  名称：

  金刚烷基溴化锌：直接制备和在交叉偶联反应中的应用

  摘要：

  DOI：

  10.1002/bkcs.10537

文献信息

• [EN] SELECTIVE VALORIZATION OF BIOMASS SUGARS<br/>[FR] VALORISATION SÉLECTIVE DE SUCRES DE BIOMASSE
  申请人：MASSACHUSETTS INST TECHNOLOGY

  公开号：WO2021127642A1

  公开（公告）日：2021-06-24

  Disclosed are methods of forming an epimer or a dehydrated isomer of a pyranose monosaccharide or a pyranose saccharide residue in an oligosaccharide or a glycoside.

  公开了在寡糖或糖苷中形成吡喃糖单糖或吡喃糖残基的对映体或脱水异构体的方法。
• [EN] NONLINEAR OPTICAL CHROMOPHORES COMPRISING A DIAMONDOID GROUP<br/>[FR] CHROMOPHORES OPTIQUES NON LINÉAIRES PRÉSENTANT UN GROUPE DIAMANTOÏDE
  申请人：LIGHTWAVE LOGIC INC

  公开号：WO2021263164A1

  公开（公告）日：2021-12-30

  Nonlinear optical chromophores having one or more diamondoid groups covalently attached to the chromophore, methods of making nonlinear optical chromophores, their use in thin films and electro-optical devices containing such nonlinear optical chromophores and thin films comprising the same. An exemplary compound is e.g.

  非线性光学色团具有一个或多个钻石烷基团与色团共价结合，制备非线性光学色团的方法，它们在薄膜中的使用以及包含这种非线性光学色团和薄膜的电光器件。一个示例化合物是例如。
• VINYL RESIN PRODUCTION METHOD
  申请人：Kuraray Co., Ltd.

  公开号：EP3130610A1

  公开（公告）日：2017-02-15

  A dispersion stabilizer in the present invention contains an aqueous emulsion (a) obtained by dispersing a polymer (A) having an ethylenically unsaturated monomer unit in an aqueous medium, a PVA (B) having a degree of saponification of 65 mol% or more and less than 82 mol% and a viscosity-average degree of polymerization of 250 or more and less than 1500, and a PVA (C) having a degree of saponification of 82 mol% or more and less than 98 mol% and a viscosity-average degree of polymerization of 1500 or more and less than 4000. The dispersion stabilizer contains: 7 to 51 mass% of the polymer (A); 40 to 84 mass% of the PVA (B); and 9 to 53 mass% of the PVA (C), with respect to a total amount of the polymer (A), the PVA (B), and the PVA (C). A vinyl resin satisfying required performance can be obtained using the dispersion stabilizer.

  本发明中的一种分散稳定剂包含一种水性乳液（a），它是通过在水性介质中分散具有乙烯基不饱和单体单元的聚合物（A）而得到的、皂化度大于或等于 65 摩尔且小于 82 摩尔，粘度-平均聚合度大于或等于 250 且小于 1500 的 PVA (B)，以及皂化度大于或等于 82 摩尔且小于 98 摩尔，粘度-平均聚合度大于或等于 1500 且小于 4000 的 PVA (C)。分散稳定剂含有就聚合物（A）、PVA（B）和 PVA（C）的总量而言，聚合物（A）的质量百分比为 7 至 51%；PVA（B）的质量百分比为 40 至 84%；PVA（C）的质量百分比为 9 至 53%。使用该分散稳定剂可获得性能符合要求的乙烯基树脂。
• DISPERSION STABILIZER FOR SUSPENSION POLYMERIZATION, AND METHOD FOR PRODUCING VINYL RESIN
  申请人：Kuraray Co., Ltd.

  公开号：EP3130611A1

  公开（公告）日：2017-02-15

  Provided is a dispersion stabilizer for suspension polymerization comprising an aqueous emulsion containing a dispersant (A), a dispersoid (B), a graft polymer (C), and an aqueous medium, wherein the dispersant (A) contains a surfactant, the dispersoid (B) contains a polymer having an ethylenically unsaturated monomer unit, the graft polymer (C) is obtained by graft polymerization of the ethylenically unsaturated monomer with the dispersant (A), a mass ratio [A/(A + B + C)] is 0.001 or more and less than 0.18, a mass ratio [C/(A + B + C)] is 0 or more and less than 0.04, and the total content of the dispersant (A), the dispersoid (B), and the graft polymer (C) is 35 to 70 mass%. A vinyl polymer to be obtained by suspension polymerization of a vinyl compound using the dispersion stabilizer has good plasticizer absorption. Further, the number of fish-eyes that occur when the vinyl polymer is formed is small, and the hue deterioration is also suppressed. Further, the dispersion stabilizer also has excellent handleability.

  本发明提供了一种用于悬浮聚合的分散稳定剂，该分散稳定剂由含有分散剂（A）、分散体（B）、接枝聚合物（C）和水介质的水乳液组成，其中分散剂（A）含有表面活性剂、接枝聚合物 (C) 是通过乙烯不饱和单体与分散剂 (A) 的接枝聚合得到的，质量比 [A/(A + B + C)] 为 0.001 或以上且小于 0.18，质量比 [C/(A + B + C)]为 0 或以上且小于 0.04，分散剂 (A)、分散体 (B) 和接枝聚合物 (C) 的总含量为 35 至 70 质量％。使用分散稳定剂对乙烯基化合物进行悬浮聚合得到的乙烯基聚合物具有良好的增塑剂吸收性。此外，乙烯基聚合物形成时出现的鱼眼数量较少，色调劣化也得到了抑制。此外，该分散稳定剂还具有极佳的操作性。
• Dispersion stabilizer for suspension polymerization, and method for producing vinyl resin
  申请人：KURARAY CO., LTD.

  公开号：US10604592B2

  公开（公告）日：2020-03-31

  Provided is a dispersion stabilizer for suspension polymerization comprising an aqueous emulsion containing a dispersant (A), a dispersoid (B), a graft polymer (C), and an aqueous medium, wherein the dispersant (A) contains a surfactant, the dispersoid (B) contains a polymer having an ethylenically unsaturated monomer unit, the graft polymer (C) is obtained by graft polymerization of the ethylenically unsaturated monomer with the dispersant (A), a mass ratio [A/(A+B+C)] is 0.001 or more and less than 0.18, a mass ratio [C/(A+B+C)] is 0 or more and less than 0.04, and the total content of the dispersant (A), the dispersoid (B), and the graft polymer (C) is 35 to 70 mass %. A vinyl polymer to be obtained by suspension polymerization of a vinyl compound using the dispersion stabilizer has good plasticizer absorption. Further, the number of fish-eyes that occur when the vinyl polymer is formed is small, and the hue deterioration is also suppressed. Further, the dispersion stabilizer also has excellent handleability.

  本发明提供了一种用于悬浮聚合的分散稳定剂，该分散稳定剂由含有分散剂（A）、分散体（B）、接枝聚合物（C）和水介质的水乳液组成，其中分散剂（A）含有表面活性剂、接枝聚合物 (C) 是通过乙烯不饱和单体与分散剂 (A) 的接枝聚合得到的，质量比 [A/(A+B+C)] 为 0.001以上且小于0.18，质量比[C/(A+B+C)]为0以上且小于0.04，分散剂(A)、分散体(B)和接枝聚合物(C)的总含量为35至70质量％。使用分散稳定剂对乙烯基化合物进行悬浮聚合得到的乙烯基聚合物具有良好的增塑剂吸收性。此外，乙烯基聚合物形成时出现的鱼眼数量较少，色调劣化也得到了抑制。此外，该分散稳定剂还具有极佳的操作性。