N-phenyl-C-2-(2,3,4,6-tetra-O-acetyl-D-glucopyranosyloxy)phenyl nitrone | 1243251-82-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-phenyl-C-2-(2,3,4,6-tetra-O-acetyl-D-glucopyranosyloxy)phenyl nitrone
• CAS: 1243251-82-2
• 化学式: C₂₇H₂₉NO₁₁
• 分子量: 543.527
• InChiKey: OFXYUAOSJCMBLN-IURCNINISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.41
• 重原子数：
  39.0
• 可旋转键数：
  9.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  149.73
• 氢给体数：
  0.0
• 氢受体数：
  11.0

反应信息

• 作为产物：
  描述：

  2-甲酰基苯基 2,3,4,6-四-O-乙酰基-beta-D-吡喃葡萄糖苷 、 苯基羟胺 以 苯 为溶剂， 以89%的产率得到N-phenyl-C-2-(2,3,4,6-tetra-O-acetyl-D-glucopyranosyloxy)phenyl nitrone
  参考文献：
  名称：

  Synthesis of O-glycosyl α-aryl nitrones

  摘要：

  alpha-Aryl nitrone are one of the most useful kinds of nitrones and have been extensively explored in recent years. However, the sugar moieties have not been introduced into these molecules before. We presented here an efficient synthesis of alpha-aryl nitrone O-glycosides via condensation of N-substituted hydroxylamine and aryl aldehydes glycosides in benzene. (C) 2010 Ying Fu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2010.04.006