glyceryl-N-(2-hydroxyethyl)carbamate | 1300663-65-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: glyceryl-N-(2-hydroxyethyl)carbamate
• 英文别名: 2,3-dihydroxypropyl N-(2-hydroxyethyl)carbamate
• CAS: 1300663-65-3
• 化学式: C₆H₁₃NO₅
• 分子量: 179.173
• InChiKey: QPYVMZXYLRHIQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  99
• 氢给体数：
  4
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  羟甲基二氧杂戊环酮 、 C.I.酸性橙108 在 rhodium(III) chloride 、 氢气 、 三苯基膦 作用下， 以 甲醇 为溶剂， 140.0 ℃ 、5.07 MPa 条件下， 反应 20.0h， 生成 glyceryl-N-(2-hydroxyethyl)carbamate
  参考文献：
  名称：

  Glycerol carboxylation to glycerol carbonate in the presence of rhodium complexes with nitrogen-containing macroligands

  摘要：

  The carboxylation of glycerol to glycerol carbonate (GC) in the presence of rhodium complexes with N-containing macroligands (polyethyleneimine and chitosan) has been studied. It has been found that the {RhCl3 + chitosan} system is an effective catalyst. It is most effective in the presence of methyl iodide or in the case of introduction of carbonates (dimethyl carbonate, propylene carbonate) into the reaction zone. The carboxylation of glycerol occurs at temperatures of 140-180 degrees C in a methanol solution in a reducing environment under a pressure of 50 atm (40 atm of CO and 10 atm of H-2). The turnover number of the rhodium catalyst for the reaction time is 10 to 120. DOI: 10.1134/S0965544112060060

  DOI：

  10.1134/s0965544112060060

文献信息

• Acetoacetyl thermosetting resin for gel coat
  申请人：Polynt Composites USA, Inc.

  公开号：US11091651B2

  公开（公告）日：2021-08-17

  Zero VOC thermosetting gel coat and laminating resin compositions, and composites and articles, are produced using a multifunctional Michael acceptor, a multifunctional Michael donor and a base catalyst. The obtained low viscosity resin is useful for producing zero VOC gel coats and laminates having excellent curability at ambient temperatures.

  零 VOC 热固性胶衣和层压树脂组合物以及复合材料和制品是利用多功能迈克尔受体、多功能迈克尔供体和基催化剂生产出来的。获得的低粘度树脂可用于生产零 VOC 胶衣和层压板，在环境温度下具有极佳的固化性。
• Acetoacetyl Thermosetting Resin for Zero VOC Gel Coat
  申请人：CCP COMPOSITES US

  公开号：US20130233739A1

  公开（公告）日：2013-09-12

  Zero VOC thermosetting gel coat and laminating resin compositions, and composites and articles, are produced using a multifunctional Michael acceptor, a multifunctional Michael donor and a base catalyst. The obtained low viscosity resin is useful for producing zero VOC gel coats and laminates having excellent curability at ambient temperatures.
• Acetoacetyl Thermosetting Resin for Gel Coat
  申请人：Polynt Composites USA Inc.

  公开号：US20160108248A1

  公开（公告）日：2016-04-21

  Zero VOC thermosetting gel coat and laminating resin compositions, and composites and articles, are produced using a multifunctional Michael acceptor, a multifunctional Michael donor and a base catalyst. The obtained low viscosity resin is useful for producing zero VOC gel coats and laminates having excellent curability at ambient temperatures.
• ACETOACETYL THERMOSETTING RESIN FOR GEL COAT
  申请人：Polynt Composites USA, Inc.

  公开号：US20180094142A1

  公开（公告）日：2018-04-05

  Zero VOC thermosetting gel coat and laminating resin compositions, and composites and articles, are produced using a multifunctional Michael acceptor, a multifunctional Michael donor and a base catalyst. The obtained low viscosity resin is useful for producing zero VOC gel coats and laminates having excellent curability at ambient temperatures.