[ytterbium(H2O)2(NO3)2(μ-NO3)(acetylacetonate)]2 | 518293-17-9

• 英文名称: [ytterbium(H2O)2(NO3)2(μ-NO3)(acetylacetonate)]2
• CAS: 518293-17-9
• 化学式: C₁₀H₂₂N₄O₂₀Yb₂
• 分子量: 864.379
• InChiKey: KHCCRAXYZZPGCI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  水 、 ytterbium(III) nitrate pentahydrate 、 N,N'-乙烯二(4-氧代-2-戊烷亚胺) 以 水 为溶剂， 生成 [ytterbium(H2O)2(NO3)2(μ-NO3)(acetylacetonate)]2
  参考文献：
  名称：

  Synthesis and X-ray crystallographic studies of complexes involving H2acacen with the early lanthanoids (H2acacen=N,N′-ethylenebis(acetylacetoneimine))

  摘要：

  The coordination properties of the Schiff base ligand N,N'-ethylenebis(acetylacetoneimine) (H(2)acacen), were investigated with a range of lanthanoid nitrate hexahydrate salts yielding [Ln(NO3)(3)(H(2)acacen)(2)][C6H12](n) (Ln = La, Pr, Nd and Sm), and X-ray crystallographic characterisation revealed that the early lanthanoids all adopt the same polymeric structure with a single, bidentate H2acacen ligand attached to each metal centre and two monodentate H(2)acacen ligands bridging between successive metal centres resulting in a polymeric array. In a similar reaction, Yb(NO3)(3).6H(2)O induced decomposition of H(2)acacen resulting in isolation of the new complex [Yb(H2O)(2)(NO3)(2)(mu-NO3)(acac)](2). (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01356-6