dinitrato (1:2,10:11-diphenyl-6,15-dimethyl-4,5,7,8,13,14,16,17-octaazacyclooctadecane-3,8,12,17-tetraene)manganese(II) | 841232-65-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dinitrato (1:2,10:11-diphenyl-6,15-dimethyl-4,5,7,8,13,14,16,17-octaazacyclooctadecane-3,8,12,17-tetraene)manganese(II)
• CAS: 841232-65-3
• 化学式: C₂₀H₂₄MnN₁₀O₆
• 分子量: 555.412
• InChiKey: XAIIBXVJAQMZJK-VLJGJFMDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  manganese (II) nitrate tetrahydrate 、 一水合肼 、 乙醛 、 邻苯二甲醛 以 甲醇 为溶剂， 以45%的产率得到dinitrato (1:2,10:11-diphenyl-6,15-dimethyl-4,5,7,8,13,14,16,17-octaazacyclooctadecane-3,8,12,17-tetraene)manganese(II)
  参考文献：
  名称：

  Synthesis and Physico‐Chemical Studies on 18‐Membered Octaazamacrocyclic Complexes of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) Ions

  摘要：

  A new series of 18-membered octaazamacrocyclic complexes [(MLX2)-X-1] and [(MLX2)-X-2] (M = Mn(11), Co(II), Ni(II), Cu(II), and Zn(II); X = Cl or NO3) have been synthesized by template condensation of o-phthalaldehyde with hydrazine hydrate and formaldehyde or acetaldehyde in MeOH. The nature of bonding and the stereochemistry of the complexes have been deduced from elemental analyses, FF-IR, H-1 NMR, EPR, UV spectroscopy, magnetic susceptibility, and conductivity measurements. An octahedral geometry has been suggested for all the complexes and the observed low molar conductance values indicate their non-ionic nature.

  DOI：

  10.1081/sim-200026200