| 63985-27-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 63985-27-3
• 化学式: C₅H₅Cl₅NOs
• 分子量: 446.566
• InChiKey: VIPWNASMUQRTBU-UHFFFAOYSA-I

反应信息

• 作为产物：
  描述：

  吡啶 、 以>99的产率得到
  参考文献：
  名称：

  [OsCl5(H2O)]−: A novel complex in osmium chemistry; reaction chemistry and solid-state structure of [AsPh4][OsCl5(H2O)]

  摘要：

  [OsCl5(H2O)](-) (2) can be isolated by solvent extraction with P(O)((OBu)-Bu-n)(3) from a product mixture obtained by the reduction of OsO4 in a chloride-containing medium. The X-ray structure analysis of [AsPh4][OsCl5(H2O)] (8) is reported. The reaction chemistry of 8 towards different Lewis-bases, such as EtOH, py, pyz is studied. 8 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00063-3