Selective Ligand Conversion of Ethylenediamine Tetraacetate to Its Triacetate on Peroxotitanate(IV)
作者:Zhao-Hui Zhou、Yuan-Fu Deng、Qiong-Xin Liu、Hua-Lin Zhang、Thomas C. W. Mak、Yuan L. Chow
DOI:10.1021/ic701256e
日期:2007.8.1
Ethylenediaminetetraacetate is converted into itstriacetate by peroxotitanate(IV), and strong chelation of the triacetate ligand to the metal center facilitates elimination of the pendant acetoxylate group. Various species of peroxotitanium(IV) complexes in the reaction sequence are fully characterized.