trans-bis(dimethylglyoxime)(pyridine)(n-tetradecyl)cobalt(III) | 157742-64-8

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: trans-bis(dimethylglyoxime)(pyridine)(n-tetradecyl)cobalt(III)
• CAS: 157742-64-8
• 化学式: C₂₇H₄₈CoN₅O₄
• 分子量: 565.702
• InChiKey: ANOSYYHXXVAFKJ-NMBSQECASA-L

反应信息

• 作为产物：
  描述：

  {pyCo(DH)2Cl} 、 溴代十四烷 以 not given 为溶剂， 以85%的产率得到trans-bis(dimethylglyoxime)(pyridine)(n-tetradecyl)cobalt(III)
  参考文献：
  名称：

  The cobaloximes trans-bis(dimethylglyoxime)(R) CoIII, R = n-C14H29 or n-C15H31. Surprising ambiphilic nature observed in the molecular packing of the longest n-alkyl organometallic compound to be structurally characterized

  摘要：

  The cobaloximes, trans-bis(dimethylglyoxime)(pyridine)(R)cobalt(III) where R = (n-tetradecyl) or (n-pentadecyl) have been synthesized and fully characterized. The crystal structure of the n-tetradecyl compound has been determined and found to be analogous to that of common ambiphilic molecules.

  DOI：

  10.1016/0022-328x(94)05311-x