tetrakis-(μ-2,2-dimethylpropanoato-O:O')bis-[(2,6-dimethylpyridine-N)copper(II)] | 295800-83-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetrakis-(μ-2,2-dimethylpropanoato-O:O')bis-[(2,6-dimethylpyridine-N)copper(II)]
• CAS: 295800-83-8
• 化学式: C₃₄H₅₄Cu₂N₂O₈
• 分子量: 745.903
• InChiKey: OARDCVMQSWJEGP-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  2,6-二甲基吡啶 、 copper(II) nitrate trihydrate 、 三甲基乙酸 在 HNO₃ 作用下， 以 sodium hydroxide 为溶剂， 生成 tetrakis-(μ-2,2-dimethylpropanoato-O:O')bis-[(2,6-dimethylpyridine-N)copper(II)]
  参考文献：
  名称：

  catena-Poly[[tetrakis(μ-3,3-dimethylbutyrato-O:O′)dicopper(II)]-μ-3,3-dimethylbutyrato-O:O′-[bis(2,6-dimethylpyridine-N)copper(II)]-μ-3,3-dimethylbutyrato-O:O′] and tetrakis(μ-2,2-dimethylpropanoato-O:O′)bis[(2,6-dimethylpyridine-N)copper(II)]

  摘要：

  The two title compounds, [Cu-3 (C6H11O2)(6)(C7H9N)(2)](n), (I), and [Cu-2(C5H9O2)(4)(C7H9N)(2)], (II), have chain and finite-molecular structures, respectively. In (I), binuclear cage units and mononuclear 2,6-dimethylpyridine complexes, both of which have inversion centres, are arranged alternately and are linked by the carboxylate ions to form one-dimensional chains along the a axis. In (II), the binuclear cage unit has an inversion centre and the coordination geometry around the Cu atom is typical square pyramidal, with 2,6-dimethylpyridine at the apical position.

  DOI：

  10.1107/s0108270100006697