isopentyl-(4-vinyl-phenyl)-ether | 116234-55-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: isopentyl-(4-vinyl-phenyl)-ether
• 英文别名: Isopentyl-(4-vinyl-phenyl)-aether；p-Isopentyloxy-styrene；1-ethenyl-4-(3-methylbutoxy)benzene
• CAS: 116234-55-0
• 化学式: C₁₃H₁₈O
• 分子量: 190.285
• InChiKey: NCOMFXGCBNGEFH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Silylated addition polymers with pendant ionic moieties
  申请人：PPG INDUSTRIES, INC.

  公开号：EP0377188A2

  公开（公告）日：1990-07-11

  Addition interpolymers with pendant ionic moieties and pendant reactable silane moieties are prepared by addition polymerization of ethylenically unsaturated monomers having ionic moieties with organofunctional silane compounds having ethylenic unsaturation in the organofunctional moiety of the silane where the silane also has reactable alkoxy and/or hydroxy groups. The addition polymerization is performed in the presence of a free radical initiator at an elevated temperature up to around 90°C and in an nonoxidizing atmosphere. The amount of the ionic monomer is effective to result in the interpolymer having at least water dispersibility and most suitably water emulsifiability and the amount of the silane monomer is in the range of about 1 to about 15 weight percent of the interpolymer. The interpolymer may be prepared with one or more additional ethylenically unsaturated monomers where the amount does not decrease the ionic character of the interpolymer below that which renders the interpolymer water emulsifiable.

  通过将具有离子基团的乙烯不饱和单体与有机官能团硅烷化合物进行加成聚合，制备具有离子基团和可反应硅烷基团的加成间聚合物，其中硅烷的有机官能团中具有乙烯不饱和基团，硅烷还具有可反应的烷氧基和/或羟基。加成聚合是在自由基引发剂存在下，在高达 90°C 左右的高温和非氧化气氛中进行的。离子单体的用量可有效地使互聚物至少具有水分散性，最适合的是水乳化性，硅烷单体的用量约为互聚物重量的 1%至 15%。可以用一种或多种额外的乙烯基不饱和单体制备互聚物，其用量不会使互聚物的离子性降低到使互聚物具有水乳化性的程度以下。
• LOW-HYGROSCOPICITY LOW-BIREFRINGENCE RESIN COMPOSITIONS, MOLDING MATERIAL OBTAINED THEREFROM, SHEET OR FILM, AND OPTICAL PART
  申请人：HITACHI CHEMICAL COMPANY, LTD.

  公开号：EP1205517A1

  公开（公告）日：2002-05-15

  Low-hygroscopicity low-birefringence resin compositions, One of the compositions is a resin composition (a) comprising the following polymers (A), and (B) and/or (C). Another is a resin composition (b) comprising the following polymers (A), (B) and (H). Still another is a polymer comprising the following polymers (I) and (J), diphenylsilicone (D), and a phenolic antioxidant (E). (A) A polymer comprising one or more kinds of indene and indene derivatives represented by the following general formula (I). (B) A.polymer comprising polystyrene or a polystyrene derivative. (C) A polymer comprising a monomer copolymerizable with styrene or a styrene derivative. (H) A graft polymer having a structure wherein a polymer comprising at least one kind of indene and an indene derivative represented by the general formula (I) bonds to a side chain of a polymer comprising a monomer copolymerizable with styrene or a styrene derivative. (I) A polymer comprising one or more kinds of indene and indene derivatives represented by the general formula (I), wherein the polymer has a heterocyclic structure in a side chain thereof. (J) A polymer comprising styrene or a styrene derivative, and a monomer copolymerizable with styrene or a styrene derivative, wherein the polymer has a carboxyl group and/or a phenolic hydroxyl group in a side chain thereof.

  低吸湿性低双折射树脂组合物，其中一种组合物是由下列聚合物（A）、（B）和/或（C）组成的树脂组合物（a）。另一种是由以下聚合物（A）、（B）和（H）组成的树脂组合物（b）。还有一种是由以下聚合物（I）和（J）、二苯基硅酮（D）和酚类抗氧化剂（E）组成的聚合物。(A) 由一种或多种茚和茚衍生物组成的聚合物，其代表通式如下（I）。(B) 由聚苯乙烯或聚苯乙烯衍生物组成的聚合物。(C) 由可与苯乙烯或苯乙烯衍生物共聚的单体组成的聚合物。(H) 具有以下结构的接枝聚合物：由通式(I)代表的至少一种茚和茚衍生物组成 的聚合物与由可与苯乙烯或苯乙烯衍生物共聚的单体组成的聚合物的侧链键 合。(I) 由通式（I）代表的一种或多种茚和茚衍生物组成的聚合物，其中聚合物的侧链具有杂环结构。(J) 由苯乙烯或苯乙烯衍生物和可与苯乙烯或苯乙烯衍生物共聚的单体组成的聚 合物，其中聚合物的侧链中含有羧基和/或酚羟基。
• COMPOSITION HAVING EXCELLENT COATING PROPERTIES
  申请人：Kuraray Co., Ltd.

  公开号：EP3904400A1

  公开（公告）日：2021-11-03

  The present invention relates to a composition containing a compound (A) represented by the following general formula (I) and a compound having two or more polymerizable functional groups (B) in a molecule (except for compound (A)), wherein a mass ratio ((A)/(B)) of the compound (A) to the compound having two or more polymerizable functional groups (B) in a multi-molecule is 30/70 to 50/50: wherein, R1 and R2 each independently represent any one selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, and an aralkyl group; R3 represents any one selected from the group consisting of an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, and an aralkyl group; R4 represents any one selected from the group consisting of a (meth)acryloyl group, a styryl group, and an alkenyl group having 2 to 6 carbon atoms; and n represents any integer of 1 to 5.

  本发明涉及一种组合物，该组合物含有由下式通式（I）表示的化合物（A）和分子中具有两个或两个以上可聚合官能团（B）的化合物（化合物（A）除外），其中化合物（A）与具有两个或两个以上可聚合官能团（B）的化合物（B）在多分子中的质量比（（A）/（B））为 30/70 至 50/50： 其中，R1 和 R2 各自独立地代表选自氢原子、具有 1 至 6 个碳原子的烷基、具有 2 至 6 个碳原子的烯基、芳基和芳烷基的任意一个；R3 代表选自具有 1 至 6 个碳原子的烷基、具有 2 至 6 个碳原子的烯基、芳基和芳烷基的任意一个； R4 代表选自（甲基）丙烯酰基、苯乙烯基和具有 2 至 6 个碳原子的烯基的任意一个；以及 n 代表 1 至 5 的任意整数。
• Block copolymers with surface-active junction groups, compositions and processes thereof
  申请人：International Business Machines Corporation

  公开号：US10259907B2

  公开（公告）日：2019-04-16

  The present invention relates to a novel block copolymer of structure 1, wherein, A- is a block polymer chain, B is a block polymer chain, wherein, A- and B- are chemically different, covalently connected polymer chains, which are phase separable and the moiety X(Y(Z)b)a is a junction group, which comprises a surface active pendant moiety Y(Z)b wherein: a is an integer from 1 to 4 denoting the number of surface active pendant moieties Y(Z)b on X, b is an integer from 1 to 5 denoting the number of Z moieties on the linking moiety Y, X is a linking group between the A polymer block, the B polymer block and the moiety Y, Y is a linking group or a direct valence bond between X and Z; and Z is a moiety independently selected from, a fluorine containing moiety, a Si1-Si8 siloxane containing moiety or a hydrocarbon moiety with at least 18 carbons, and further wherein the junction group X(Y(Z)b)a has a surface energy less than that that of the block A and less than that of the block B. The invention also relates to a composition comprising the novel copolymer and its use in direct self-assembly processes.

  本发明涉及一种结构为 1 的新型嵌段共聚物、 其中，A- 是嵌段聚合物链，B 是嵌段聚合物链、 其中，A- 和 B-是化学性质不同的共价连接聚合物链，可相分离，分子 X(Y(Z)b)a 是连接基团，包括表面活性悬垂分子 Y(Z)b ，其中 a 是 1 到 4 之间的整数，表示 X 上表面活性悬垂分子 Y(Z)b 的数量、 b 是 1 至 5 的整数，表示连接分子 Y 上 Z 分子的数目、 X 是 A 聚合物嵌段、B 聚合物嵌段和分子 Y 之间的连接基团、 Y 是 X 和 Z 之间的连接基团或直接价键；以及 本发明还涉及一种包含新型共聚物的组合物及其在直接自组装工艺中的应用。
• Responsive microgel and methods related thereto
  申请人：——

  公开号：US20030152623A1

  公开（公告）日：2003-08-14

  A responsive microgel is provided which responds volumetrically and reversibly to a change in one or more aqueous conditions selected from the group consisting of (temperature, pH, and ionic conditions) comprised of an ionizable network of covalently cross-linked homopolymeric ionizable monomers wherein the ionizable network is covalently attached to an amphiphilic copolymer to form a plurality of ‘dangling chains’ and wherein the ‘dangling chains’ of amphiphilic copolymer form immobile micelle-like aggregates in aqueous solution. A responsive microgel is further provided that comprises at least one therapeutic entity and delivers a substantially linear and sustained release of the therapeutic entity under physiological conditions.

  本发明提供了一种响应型微凝胶，该微凝胶可对选自由温度、pH 值和离子条件组成的组中的一种或多种水性条件的变化作出体积上和可逆的响应、和离子条件）组成的共价交联均聚可离子化单体的可离子化网络，其中可离子化网络与两性共聚物共价连接，形成多条 "悬链"，两性共聚物的 "悬链 "在水溶液中形成不动的胶束状聚集体。还提供了一种响应性微凝胶，它包含至少一种治疗实体，并能在生理条件下提供治疗实体的线性和持续释放。