[Pd(N-acetyl-2-phenylbenzimidazole)(μ-Cl)]2 | 182481-16-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: [Pd(N-acetyl-2-phenylbenzimidazole)(μ-Cl)]2
• 英文别名: chloropalladium(1+);1-(2-phenylbenzimidazol-1-yl)ethanone
• CAS: 182481-16-9
• 化学式: C₃₀H₂₂Cl₂N₄O₂Pd₂
• 分子量: 754.276
• InChiKey: LUAXUSZLBDEEIA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-acetyl-2-phenylbenzimidazole 以 二氯甲烷 、 溶剂黄146 为溶剂， 生成 [Pd(N-acetyl-2-phenylbenzimidazole)(μ-Cl)]2
  参考文献：
  名称：

  A way to obtain cyclopalladation of unsubstituted 2-phenylimidazole derivatives

  摘要：

  This work shows the difficulties of obtaining cyclopalladated complexes with 2-phenylimidazole and 2-phenylbenzimidazole as ligands. The protection of the NH group in the heterocycle with an acetyl group allows the formation of several cyclopalladated complexes of both ligands. The X-ray structure of the dimeric acetate-bridge complex of N-acetyl-2-phenyl-benzimidazole is described. The subsequent displacement of the protective group affords a monomeric cyclopalladated complex of 2-phenylbenzimidazole, as well as a coordination complex of this ligand.

  DOI：

  10.1016/0022-328x(96)06148-7