(Di-pyridin-2-yl-methyl)-(di-pyridin-2-yl-methylene)-amine | 213617-14-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (Di-pyridin-2-yl-methyl)-(di-pyridin-2-yl-methylene)-amine
• CAS: 213617-14-2
• 化学式: C₂₂H₁₇N₅
• 分子量: 351.41
• InChiKey: FCBSJWZPPVXWCN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.89
• 重原子数：
  27.0
• 可旋转键数：
  5.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  63.92
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  (Di-pyridin-2-yl-methyl)-(di-pyridin-2-yl-methylene)-amine 在 manganese(IV) oxide 、 溶剂黄146 作用下， 反应 1.0h， 生成 1,3,3-Tris(2-pyridyl)-3H-imidazo[1,5-a]pyridin-4-ium nitrate
  参考文献：
  名称：

  Isolation and characterization of an oxidative degradation product of a polypyridine ligand

  摘要：

  讨论了多吡啶配体在氧化条件下易碎的成因。

  DOI：

  10.1039/a803255f
• 作为产物：
  描述：

  2-二吡啶基酮 、 1,1-双(吡啶-2-基)甲胺 在 溶剂黄146 作用下， 以 异丙醇 为溶剂， 反应 5.0h， 生成 (Di-pyridin-2-yl-methyl)-(di-pyridin-2-yl-methylene)-amine
  参考文献：
  名称：

  Isolation and characterization of an oxidative degradation product of a polypyridine ligand

  摘要：

  讨论了多吡啶配体在氧化条件下易碎的成因。

  DOI：

  10.1039/a803255f

文献信息

• Preparation and Crystal Structures of Manganese, Iron, and Cobalt Complexes of the Bis[di(2-pyridyl)methyl]amine (bdpma) Ligand and Its Oxidative Degradation Product 1,3,3-Tris(2-pyridyl)-3H-imidazo[1,5-a]pyridin-4-ium (tpip); Origin of the bdpma Fragility
  作者：Catherine Hemmert、Michael Renz、Heinz Gornitzka、Stéphanie Soulet、Bernard Meunier

  DOI：10.1002/(sici)1521-3765(19990604)5:6<1766::aid-chem1766>3.0.co;2-z

  日期：1999.6.4

  The synthesis and structural characterization of manganese, iron, and cobalt complexes of bis[di(2-pyridyl)methyl]amine (bdpma) were investigated. The bdpma ligand can give rise to mono- or dimeric complexes. Moreover, bdpma can undergo oxidative degradation leading to 1,3,3-tris(2-pyridyl)-3H-imidazo[1,5-a]pyridin-4-ium (tpip) or to starting materials used for the preparation of bdpma. During attempts to prepare manganese, iron, or cobalt complexes of the tpip ligand, two classes of compounds were obtained. The first class corresponded to the tpip cation with a simple exchange of counterion and the second class led to a new type of complex, which involved a modification of tpip and contained the N-(di(2-pyridyl)methoxymethyl)(di(2-pyridyl)imine) (dpmmdpi) ligand. This work has allowed us to understand the fragility of the bdpma ligand, which is due to the easily activated benzylic C-H bonds in the a position to the heteroatom.