4-octadecylaminopyridine | 150892-88-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4-octadecylaminopyridine
• 英文别名: N-octadecylpyridin-4-amine
• CAS: 150892-88-9
• 化学式: C₂₃H₄₂N₂
• 分子量: 346.6
• InChiKey: ADNNMLLTNLEDOK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  25
• 可旋转键数：
  18
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  24.9
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-octadecylaminopyridine 在 H₂O 、 O₂ 作用下， 以 甲醇 为溶剂， 生成 {pentacyano(4-octadecylaminopyridine)ferrate(III)}(hexadecyltrimethylammonium)2 dihydrate
  参考文献：
  名称：

  Armand, Franck; Sakuragi, Hirochika; Tokumaru, Katsumi, New Journal of Chemistry, 1993, vol. 17, p. 351 - 356

  摘要：

  DOI：
• 作为产物：
  描述：

  4-溴吡啶 、 十八胺 生成 4-octadecylaminopyridine
  参考文献：
  名称：

  Solvent effect on the charge-transfer transition of a novel amphiphilic pentacyano(4-octadecylaminopyridine)ferrate(III) complex

  摘要：

  Pentacyano(4-octadecylaminopyridine)ferrate(III) amphiphilic complex is made soluble in a large range of solvents by a suitable choice of counter cations. The ligand-to-metal charge-transfer transition which takes place in the hydrophilic part is very sensitive to the nature of the solvent. The solvatochromic behaviour of this organometallic compound is described and shown to correlate with the Gutmann acceptor number (AN). Both the solubility and solvatochromic properties clearly indicate the importance of hydrogen bonding in the solute–solvent interactions, a result that is further confirmed by a preferential solvation of the chromophore by methanol molecules in methanol–chloroform mixtures.

  DOI：

  10.1039/ft9938901021

文献信息

• METHOD OF PRODUCING PRUSSIAN BLUE-TYPE METAL COMPLEX NANOPARTICLES, AND PRUSSIAN BLUE-TYPE METAL COMPLEX NANOPARTICLES OBTAINED BY THE METHOD, DISPERSION OF THE NANOPARTICLES, METHOD OF REGULATING THE COLOR OF THE NANOPARTICLES, AND ELECTRODE AND TRANSMITTED LIGHT-REGULATOR EACH USING THE NANOPARTICLES
  申请人：Kawamoto Tohru

  公开号：US20100133487A1

  公开（公告）日：2010-06-03

  To provide a method of producing Prussian blue-type metal complex nanoparticles without necessarily requiring complicated steps and an excessive amount of raw materials, but allowing one to obtain nanometer-size fine particles having desired fine particle properties, and Prussian blue-type metal complex nanoparticles obtained by the method, a dispersion of the nanoparticles, a method of regulating the color of the nanoparticles, and an electrode and a transmitted light-regulator each using the nanoparticles; Prussian blue-type metal complex nanoparticles are produced by: mixing an aqueous solution containing a metal cyano complex anion having predetermined metal atom M A as a central metal and an aqueous solution containing a cation of predetermined metal atom M B , thereby precipitating the crystal of a Prussian blue-type metal complex having the metal atom M A and the metal atom M B ; and then mixing the Prussian blue-type metal complex with an aqueous solution containing a metal cyano complex anion having the metal atom M C as a central metal and/or an aqueous solution containing a cation of the metal atom M D . The thus-obtained Prussian blue-type metal complex nanoparticles have a preferable electrochemical responsiveness, and the particles can be used for forming a thin film including them to construct a light-transmitted regulator.

  提供一种生产普鲁士蓝型金属配合物纳米颗粒的方法，无需复杂步骤和过多原材料，但可以获得所需的纳米级细颗粒性能，以及通过该方法获得的普鲁士蓝型金属配合物纳米颗粒、颗粒分散液、调节颗粒颜色的方法，以及使用该颗粒的电极和透光调节器；生产普鲁士蓝型金属配合物纳米颗粒的方法为：混合含有预定金属原子MA作为中心金属的金属氰配合物阴离子的水溶液和含有预定金属原子MB阳离子的水溶液，从而沉淀出具有金属原子MA和金属原子MB的普鲁士蓝型金属配合物晶体；然后将普鲁士蓝型金属配合物与含有金属原子MC作为中心金属的金属氰配合物阴离子和/或含有金属原子MD阳离子的水溶液混合。因此获得的普鲁士蓝型金属配合物纳米颗粒具有良好的电化学响应性，可以用于形成包含它们的薄膜，以构建透光调节器。
• METHOD OF REGULATING THE COLOR OF PRUSSIAN BLUE TYPE METAL COMPLEX NANOPARTICLES, PRUSSIAN BLUE TYPE METAL COMPLEX NANOPARTICLE OBTAINED BY THE SAME, DISPERSION OF THE NANOPARTICLES, ELECTRODE AND TRANSMITTED-LIGHT REGULATOR BOTH EMPLOYING THE NANOPARTICLES
  申请人：National Institute of Advanced Industrial Science and Technology

  公开号：EP2116511B1

  公开（公告）日：2018-04-18
• ULTRAFINE PARTICLES OF PRUSSIAN BLUE-TYPE METAL COMPLEX, DISPERSION LIQUID THEREOF AND THEIR PRODUCTION METHODS
  申请人：Kawamoto Tohru

  公开号：US20090211494A1

  公开（公告）日：2009-08-27

  Disclosed is a method for producing ultrafine particles of a Prussian blue-type metal complex wherein (A) an aqueous solution containing an anionic metal cyano complex having a metal atom M 1 as the central metal is mixed with an aqueous solution containing metal cations of a metal atom M 2 for precipitating a crystal of a Prussian blue-type metal complex having the metal atom M 1 and the metal atom M 2 ; then (B) a solution obtained by dissolving a ligand L in a solvent is mixed with the crystal of the Prussian blue-type metal complex for forming a dispersion liquid of ultrafine particles of the Prussian blue-type metal complex; and the (C) the Prussian blue-type metal complex is separated from the dispersion liquid as nanometer-sized ultrafine particles.
• METAL COMPLEX NANOPARTICLES AND METHOD FOR PRODUCING THE SAME
  申请人：KAWAMOTO Tohru

  公开号：US20120077037A1

  公开（公告）日：2012-03-29

  A method for producing metal complex nanoparticles, the method having: providing an aqueous solution containing a metal cyano complex anion having a metal atom M A as a central metal, with an aqueous solution containing zinc cation, the pH of the aqueous solution containing zinc cation being adjusted; and mixing the solutions and thereby producing metal complex nanoparticles composed of the metal atom M A and zinc under controlling the properties of the obtained metal complex nanoparticles.
• US4107313A
  申请人：——

  公开号：US4107313A

  公开（公告）日：1978-08-15