[Ru(1-((4'-methyl-2,2'-bipyridin-4-yl)methyl)-1'-methyl-4,4'-bipyridinediium)(10-((4'-methyl-2,2'-bipyridin-4-yl)methyl)phenothiazine)2](4+) | 256481-99-9

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [Ru(1-((4'-methyl-2,2'-bipyridin-4-yl)methyl)-1'-methyl-4,4'-bipyridinediium)(10-((4'-methyl-2,2'-bipyridin-4-yl)methyl)phenothiazine)2](4+)
• 英文别名: [Ru(bpyCH2MV(2+))(bpyCH2PTZ)2](4+)
• CAS: 256481-99-9
• 化学式: C₇₁H₆₀N₁₀RuS₂
• 分子量: 1218.53
• InChiKey: RHEPCBGDVCSVLO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 dichlorotetrakis(dimethylsulfoxide)ruthenium(II) 、 1-((4'-methyl-2,2'-bipyridin-4-yl)methyl)-1'-methyl-4,4'-bipyridinediium hexafluorophosphonate 、 10-<(4'-methyl-2',2-bipyridin-4-yl)methyl>phenothiazine 、 4'-甲基-2,2'-联吡啶-4-甲酸 以 乙醇 、 水 为溶剂， 以19%的产率得到(4'-methyl-2,2'-bipyridine-4-carboxylic acid)[1-((4'-methyl-2,2'-bipyridin-4-yl)methyl)-1'-methyl-4,4'-bipyridiniium][10-((4'-methyl-2,2'-bipyridin-4-yl)methyl)phenothiazine]ruthenium(II) hexafluorophosphate
  参考文献：
  名称：

  One-Pot Synthesis and Characterization of a Chromophore−Donor−Acceptor Assembly

  摘要：

  The acid-functionalized tris-heteroleptic chromophore-donor-acceptor assembly [Ru-II(bpyCOOH)(bpyCH(2)PTZ)(bpyCH(2)MV(2+))](PF6)(4)](4+) (1) (bpyCOOH = 4'-methyl-2,2'-bipyridine-4-carboxylic acid; bpyCH(2)PTZ = 10-((4'-methyl-2,2'-bipyridin-4-yl)methyl)phenothiazine; bpyCH(2)MV(2+) = 1-((4'-methyl-2,2'-bipyridin-4-yl)methyl)1'-methyl-4,4'-bipyridinediium) was synthesized in a one-pot reaction by careful selection of the order of ligand addition to RuCl2(DMSO)(4) (DMSO = dimethyl sulfoxide). The success of this method was based upon separation and isolation of 1 from mixtures containing ligand-scrambled products by cation exchange chromatography. Metal-to-ligand charge-transfer (MLCT) excitation in acetonitrile at 464 nm was followed by intramolecular electron transfer to give a redox-separated state [Ru-II(bpyCOOH)(bpyCH(2)PTZ(.+))(bpyCH(2)MV(.+))](4+) with an efficiency of eta(RS) = 0.35 +/- 0.05.

  DOI：

  10.1021/ic990512i