| 228098-52-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 228098-52-0
• 化学式: C₁₅H₁₅CuN₃O₄
• 分子量: 364.848
• InChiKey: ZPMKGWNXSVBTLX-MCLJSLMOSA-L

反应信息

• 作为产物：
  描述：

  2-氨基吡啶 、 N-salicylidene-L-serinatoaquacopper(II) monohydrate 以 乙醇 、 水 为溶剂， 以22%的产率得到
  参考文献：
  名称：

  Crystal structures of the N-salicylidene–L-serinatoaquacopper(II) monohydrate and its ternary derivative with 2-aminopyridine

  摘要：

  The complexes [Cu(Sal-(L-Ser))H2O]. H2O 1 and [Cu(Sal-Ser)(2-amino pyridine)] 2 have been prepared and their crystal structures determined. In 1 the copper(II) has a square-pyramidal geometry, being coordinated to the uidentate Sal-(L-Ser) Schiff base ligand and the oxygen atom (O(16)) of one water molecule occupying the corners of a square. The coordination sphere about the copper is completed by an axial O(12) atom of an hydroxyl group belonging to an adjacent complex unit. In the racemic ternary complex 2 the metal atom has a square-planar coordination with O,N,O atoms of the bidentate Sal-Ser dianion and the heterocyclic N atom of the 2-aminopyridine. Spectroscopic data are discussed. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00373-8