N-phenyl-1-[2-[[2-(phenyliminomethyl)phenyl]diselanyl]phenyl]methanimine | 1401244-70-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-phenyl-1-[2-[[2-(phenyliminomethyl)phenyl]diselanyl]phenyl]methanimine
• CAS: 1401244-70-9
• 化学式: C₂₆H₂₀N₂Se₂
• 分子量: 518.378
• InChiKey: SJCMRFRYYAVROC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.46
• 重原子数：
  30
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-氯苯甲醛 在 六甲基磷酰三胺 、 sodium diselenide 作用下， 以 四氢呋喃 、 乙腈 为溶剂， 反应 18.0h， 生成 N-phenyl-1-[2-[[2-(phenyliminomethyl)phenyl]diselanyl]phenyl]methanimine
  参考文献：
  名称：

  Azomethine diselenides: Supramolecular structures and facile formation of a bis-oxazoline diselenide

  摘要：

  A series of N2Se2 and N2Se2O2 acyclic Schiff base diselenides (3-9) have been synthesized by condensation of bis(o-formylphenyl) diselenide and amines (aniline, p-bromoaniline, benzylamine, ethanolamine, 1-aminopropanol, 2-aminophenol). The Schiff base diselenides were characterized by elemental analysis, ESI-MS, NMR (H-1, C-13, Se-77) spectroscopy and X-ray crystallography. During crystallization compound 6 afforded bis(phenyloxazoline) diselenide 9 via cyclization of Schiff base of ethanolamine. The supramolecular nature of these diselenides is studied by X-ray crystallographic structure analysis. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.07.026

文献信息

• Azomethine diselenides: Supramolecular structures and facile formation of a bis-oxazoline diselenide
  作者：Snigdha Panda、Pradip Kr. Dutta、G. Ramakrishna、C. Malla Reddy、Sanjio S. Zade

  DOI：10.1016/j.jorganchem.2012.07.026

  日期：2012.10

  A series of N2Se2 and N2Se2O2 acyclic Schiff base diselenides (3-9) have been synthesized by condensation of bis(o-formylphenyl) diselenide and amines (aniline, p-bromoaniline, benzylamine, ethanolamine, 1-aminopropanol, 2-aminophenol). The Schiff base diselenides were characterized by elemental analysis, ESI-MS, NMR (H-1, C-13, Se-77) spectroscopy and X-ray crystallography. During crystallization compound 6 afforded bis(phenyloxazoline) diselenide 9 via cyclization of Schiff base of ethanolamine. The supramolecular nature of these diselenides is studied by X-ray crystallographic structure analysis. (C) 2012 Elsevier B. V. All rights reserved.