2-(2-methoxyphenyl)-3,4-diphenylbenzo[4,5]thieno[2,3-c]pyridin-1(2H)-one | 1581713-75-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 2-(2-methoxyphenyl)-3,4-diphenylbenzo[4,5]thieno[2,3-c]pyridin-1(2H)-one
• CAS: 1581713-75-8
• 化学式: C₃₀H₂₁NO₂S
• 分子量: 459.568
• InChiKey: SBPTZHNGCYKQQD-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 二苯基乙炔 以 甲苯 为溶剂， 反应 12.0h， 以69%的产率得到2-(2-methoxyphenyl)-3,4-diphenylbenzo[4,5]thieno[2,3-c]pyridin-1(2H)-one
  参考文献：
  名称：

  Intramolecular heterocyclization and cyclopalladation of selenoanisole substituted propargyl imines: Synthesis and reactivity of Pd–C bond towards alkynes

  摘要：

  The intramolecular cyclization of o-SeMeC6H4C CC-(CF3)(=NAr) with [PdCl2(PhCN)(2)] to dimeric cyclopalladated benzoselenophene has been developed under mild conditions. The reactivity of the new dimeric cyclopalladated benzoselenophene is examined towards insertion of alkynes into Pd-C bond. The reactivity study is also extended to Pd-C bond of dimeric cyclopalladated benzothiophenes towards insertion of alkynes. (C) 2014 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2014.01.028