| 154395-02-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 154395-02-5
• 化学式: C₄H₈O*C₁₀H₁₃O*Na
• 分子量: 244.309
• InChiKey: PRBVYXUSRBFADO-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  plumbocene 、 以 甲苯 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Synthesis and structure of [Cp2PbCpthf  Na]·0.5thf; implications to the control of dimensionality in p block metallocene anion systems (Cp = C5H5, Cpthf = {C5H4}CH2C4H7O)

  摘要：

  The title compound [Cp2PbCpthfNa]·0.5thf 1, obtained from the addition reaction of Cp2Pb with [CpthfNa·thf], provides the first opportunity to assess the structural impact of internal donation on aggregation within a p block metal cyclopentadienide anion system; the result being the adoption of an unusual polymeric sheet structure composed of [Cp2PbCpthfNa]3 rings.

  DOI：

  10.1039/b004608f