bis-(5,11,17,23-tert-butyl-25,26,27.28-(2-mercaptoethoxy))tetramercury(II) calix[4]arene | 286413-81-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: bis-(5,11,17,23-tert-butyl-25,26,27.28-(2-mercaptoethoxy))tetramercury(II) calix[4]arene
• CAS: 286413-81-8
• 化学式: C₁₀₄H₁₃₆Hg₄O₈S₈
• 分子量: 2573.11
• InChiKey: MYCCWJNHCDNHPN-UHFFFAOYSA-F

反应信息

• 作为产物：
  描述：

  bis-(5,11,17,23-tert-butyl-25,26,27-(2-mercaptoethoxymercuriomethyl)-28-(2-mercaptoethoxy))mercury(II) calix[4]arene 以 neat (no solvent) 为溶剂， 生成 bis-(5,11,17,23-tert-butyl-25,26,27.28-(2-mercaptoethoxy))tetramercury(II) calix[4]arene
  参考文献：
  名称：

  Calix[4]arenes with narrow rim 2-mercaptoethoxy substituents as potential precursor molecules for metallacages and sensors

  摘要：

  The compound 5,11,17,23-tert-butyl-25,26,27,28-(2-mercaptoethoxy) calix[4]arene reacts with methylmercuric acetate to give 5,11,17,23-tert-butyl-25,26,27,28-(2-mercaptoethoxymercuriomethyl) calix[4]arene. Under vacuum this compound converts to bis-(5,11,17,23-tert-butyl-25,26,27-(2-mercaptoethoxymarcuriomethyl)-28-(2-mercaptoethoxy))mercury calix[4]arene by loss of dimethylmercury. Additional loss of dimethylmercury gave a product that is intermediate between bis-(5,11,17,23-tert-butyl-25,26(2-mercaptoethoxymercuriomethyl)-27,28-(2-mercaptoethoxy))dimercury calix[4]arene, bis-(5,11,17,23-tert-butyl-25-(2-mercaptoethoxymercuriomethyl)-26,27,28-(2-mercaptoethoxy))trimercury calix[4]arene, and the cluster bis-(5,11,17,23-tert-butyl-25,26,27,28-(2-mercaptoethoxy))tetramercury calix[4]arene (11). 5,11,17,23-Tert-butyl-25,26,27,28-(2-mer calix[4]arene reacts with 9-chloromethylanthracene to give 5,11,17,23-tert-butyl-25,26,27,28-(9-thiomethylanthracylethoxy) calix[4]arene. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00577-0