trans-bis(pyridine-N)bis(2-thiopheneglyoxylato-O(1),O(2))copper(II) | 226235-27-4

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: trans-bis(pyridine-N)bis(2-thiopheneglyoxylato-O(1),O(2))copper(II)
• CAS: 226235-27-4
• 化学式: C₂₂H₁₆CuN₂O₆S₂
• 分子量: 532.057
• InChiKey: QDRLCWLIWMIDEI-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  吡啶 、 [Cu(2-thiopheneglyoxylato)2(H2O)2] 以 甲醇 为溶剂， 生成 trans-bis(pyridine-N)bis(2-thiopheneglyoxylato-O(1),O(2))copper(II)
  参考文献：
  名称：

  Copper(II) 2-thiopheneglyoxylate adducts with pyridine derivatives

  摘要：

  In the crystals of trans-bis(pyridine-N)bis(2-thiopheneglyoxylato-O-1,O-2)copper(II), [Cu(C6H3O3S)(2)(C5H5N)(2)], there is a mononuclear Cu-II complex molecule. In the crystal of catena-poly[[[bis(2-thiopheneglyoxylato-O-1,O-2)copper(II)]-mu-(2-thiopheneglyoxylato-O-1:O-1,O-2)[bis(3-methylpyridine-N)copper(II)] -mu-(2-thiopheneglyoxylato-O-1,O-2:O-1)] monohydrate], {[Cu-2(C6H3O3S)(4)(C6H7N)(2)]. H2O}(n), there is a zigzag polymer chain where the Cu-II atoms are bridged by the thiopheneglyoxylate ions. In the crystal of cis-bis(4-methylpyridine-N)bis(2-thiopheneglyoxylato-O-1,O-2)copper(II), [Cu(C6H3O3S)(2)(C6H7N)(2)], there is a mononuclear Cu-II complex. The coordination geometry around the Cu atoms is distorted octahedral. Each thiopheneglyoxylate ion adopts a flattened structure and forms a five-membered chelate ring with the Cu atom.

  DOI：

  10.1107/s0108270198016424