5,6-diamino-1,10-phenanthrolinebis(2,2'-bipyridine)ruthenium(II)(2+) | 213908-24-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 5,6-diamino-1,10-phenanthrolinebis(2,2'-bipyridine)ruthenium(II)(2+)
• 英文别名: Ru(2,2'-bipyridine)2(9,10-diamino phenanthroline)(2+)；[Ru(bpy)2(5,6-diamino-1,10-phenathroline)](2+)
• CAS: 213908-24-8
• 化学式: C₃₂H₂₆N₈Ru
• 分子量: 623.682
• InChiKey: ZFMYSVZZCLBCMZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  5,6-diamino-1,10-phenanthrolinebis(2,2'-bipyridine)ruthenium(II)(2+) 、 芘- 4,5,9,10 -四酮 以 水 、 溶剂黄146 、 乙腈 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  Observation of supramolecular π–π dimerization of a dinuclear ruthenium complex by 1H NMR and ESMS

  摘要：

  双核钌络合物bis{dipyrido[3,2-f:2′,3′-h]quinoxalo}[2,3-e:2′,3′-l]pyrene (bqpy) 在溶液中形成二聚体，这些二聚体仅通过桥接配体的π–π堆积维持，足够稳定，不仅可以通过1H NMR光谱法观察到，还可以通过低加速锥电压的电喷雾质谱法观察到。

  DOI：

  10.1039/a805809a
• 作为产物：
  描述：

  在 N₂H₄*H₂O 、 Pd/C 作用下， 以 not given 为溶剂， 以89%的产率得到5,6-diamino-1,10-phenanthrolinebis(2,2'-bipyridine)ruthenium(II)(2+)
  参考文献：
  名称：

  Observation of supramolecular π–π dimerization of a dinuclear ruthenium complex by 1H NMR and ESMS

  摘要：

  双核钌络合物bis{dipyrido[3,2-f:2′,3′-h]quinoxalo}[2,3-e:2′,3′-l]pyrene (bqpy) 在溶液中形成二聚体，这些二聚体仅通过桥接配体的π–π堆积维持，足够稳定，不仅可以通过1H NMR光谱法观察到，还可以通过低加速锥电压的电喷雾质谱法观察到。

  DOI：

  10.1039/a805809a

文献信息

• Diamine derivative of a ruthenium(II)-polypyridyl complex for chemodosimetric detection of nitrite ion in aqueous solution
  作者：Amrita Ghosh、Priyadip Das、Sukdeb Saha、Tanmay Banerjee、Harshad B. Bhatt、Amitava Das

  DOI：10.1016/j.ica.2011.01.066

  日期：2011.6

  Nitrite is quite an abundant anion in the environment. It, however, becomes toxic to human life, as well as aquatic animals when present above the permissible concentration level. We have reported here a Ru(II)-polypyridyl-based complex (1) for chemodosimetric detection of nitrite ion in aqueous solution. Formation of the new triazole based complex, generated by reaction of 1 and N2O3, is ascertained by comparing its properties with a presynthesised triazole complex. (C) 2011 Elsevier B. V. All rights reserved.
• Synthesis, characterization, DNA-binding and DNA-photocleavage studies of [Ru(bpy)2(pmip)]2+ and [Ru(phen)2(pmip)]2+ (pmip=2-(2′-pyrimidyl)imidazo[4,5-f][1,10]phenanthroline
  作者：Shuo Shi、Tian Xie、Tian-Ming Yao、Chao-Ran Wang、Xiao-Ting Geng、Dan-Jing Yang、Lin-Jie Han、Liang-Nian Ji

  DOI：10.1016/j.poly.2009.02.035

  日期：2009.5

  Two new Ru(II) complexes, [Ru(bpy)(2)(pmip)](2+) (1) and [Ru(phen)(2)(pmip)](2+) (2), have been synthesized and characterized by elemental analysis, ESI-MS and H-1 NMR spectra. Their DNA-binding properties were studied by means of UV-VIS, emission and CD spectra, thermal denaturation and viscosity measurements as well as their DNA-photocleavage properties. The experimental results show that both 1 and 2 can bind to DNA in an intercalative mode; the DNA-binding affinity of 2 is greater than that of 1, which suggests that the ancillary ligands have a significant effect on the spectroscopic properties and DNA-binding behavior of the Ru(II) complexes. Under irradiation with UV light, the Ru(II) complexes show excellent efficiency of cleaving DNA. This research may provide valuable insight into the interactions of metal complexes with DNA, knowledge that is an excellent backdrop for the rational design of promising drugs. (C) 2009 Elsevier Ltd. All rights reserved.