2-(2-ethoxyethyl)-N,N,N',N'-tetraethylmalondiamide | 246855-54-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-(2-ethoxyethyl)-N,N,N',N'-tetraethylmalondiamide
• 英文别名: 2-(2-ethoxyethyl)-N,N,N',N'-tetraethylpropanediamide
• CAS: 246855-54-9
• 化学式: C₁₅H₃₀N₂O₃
• 分子量: 286.415
• InChiKey: FWLKRORFJLZQJM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  20
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  49.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  lanthanum(III) nitrate hexahydrate 、 2-(2-ethoxyethyl)-N,N,N',N'-tetraethylmalondiamide 以 乙醇 为溶剂， 生成 bis[2-(2-ethoxyethyl)-N,N,N',N'-tetraethylmalondiamide-O(1),O(3)]tris(nitrato-O,O')lanthanum(III)
  参考文献：
  名称：

  Bis[2-(2-ethoxyethyl)-N,N,N',N'-tetraethylmalondiamide-O¹,O³]tris(nitrato-O,O')lanthanum(III)

  摘要：

  2-(2-Ethoxyethyl)-N,N,N',N'-tetraethylmalondiamide (TEEEMA, C15H30N2O3) reacts with lanthanum(III) nitrate to give the title complex, [La(NO3)(3)(TEEEMA)(2)], in which the two carboxyl functions of each TEEEMA ligand are bonded to the metal ion together with three bidentate nitrate ions. This structure establishes that the ether O atom of the central chain of TEEEMA is not bonded to the metal ion, at least in the solid state. The coordination environment geometry is different from that of the lanthanum complex of N,N,N',N'-tetraethylmalondiamide (TEMA).

  DOI：

  10.1107/s0108270199008215