4-[[31-[(2,6-Dipyridin-2-ylpyridin-4-yl)oxymethyl]-2,5,8,11,18,21,24,27-octaoxatricyclo[26.4.0.012,17]dotriaconta-1(28),12(17),13,15,29,31-hexaen-14-yl]methoxy]-2,6-dipyridin-2-ylpyridine | 1529776-29-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4-[[31-[(2,6-Dipyridin-2-ylpyridin-4-yl)oxymethyl]-2,5,8,11,18,21,24,27-octaoxatricyclo[26.4.0.012,17]dotriaconta-1(28),12(17),13,15,29,31-hexaen-14-yl]methoxy]-2,6-dipyridin-2-ylpyridine
• 英文别名: 4-[[31-[(2,6-dipyridin-2-ylpyridin-4-yl)oxymethyl]-2,5,8,11,18,21,24,27-octaoxatricyclo[26.4.0.012,17]dotriaconta-1(28),12(17),13,15,29,31-hexaen-14-yl]methoxy]-2,6-dipyridin-2-ylpyridine
• CAS: 1529776-29-1
• 化学式: C₅₆H₅₄N₆O₁₀
• 分子量: 971.079
• InChiKey: FCBWVIRNUIWSDA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  72
• 可旋转键数：
  10
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  170
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  4-[[31-[(2,6-Dipyridin-2-ylpyridin-4-yl)oxymethyl]-2,5,8,11,18,21,24,27-octaoxatricyclo[26.4.0.012,17]dotriaconta-1(28),12(17),13,15,29,31-hexaen-14-yl]methoxy]-2,6-dipyridin-2-ylpyridine 在 zinc trifluoromethanesulfonate 作用下， 生成
  参考文献：
  名称：

  Photo-induced secondary assembly of bis(terpyridyl)dibenzo-24-crown-8/Zn2+ supramolecular polymer

  摘要：

  A crown ether-based supramolecular gel with a three-dimensional network structure was successfully constructed via a hierarchical induced assembly strategy and characterized by UV/vis NMR, viscometry and DLS. Therein, the coordination linkage of bis(terpyridyl)dibenzo-24-crown-8 1 with Zn2+ produces the 1/Zn2+ supramolecular polymer as the primary assembly. Then, the anthryl-dibenzylammonium guest 2 was grafted to the 1/Zn2+ supramolecular polymer via the non-covalent association of dibenzylammonium moieties on guests with the dibenzo-24-crown-8 rings on supramolecular polymer. Furthermore, the supramolecular polymer with anthryl grafts underwent a photo-induced secondary assembly to produce the supramolecular gel, which could be reversibly disassembled by a thermoinduced dissociation of anthracene dimers. These photo/thermo-induced hierarchical assembly/disassembly behaviors will provide a potential way to construct degradable hierarchical supramolecular assemblies employing environment-friendly external stimuli, such as light and heat, as controlling method. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2015.04.014
• 作为产物：
  描述：

  trans-bis(hydroxymethylbenzo)-24-crown-8 、 4'-氯-2,2':6',2''-三联吡啶 在 potassium hydroxide 作用下， 以 二甲基亚砜 为溶剂， 反应 24.0h， 以50%的产率得到4-[[31-[(2,6-Dipyridin-2-ylpyridin-4-yl)oxymethyl]-2,5,8,11,18,21,24,27-octaoxatricyclo[26.4.0.012,17]dotriaconta-1(28),12(17),13,15,29,31-hexaen-14-yl]methoxy]-2,6-dipyridin-2-ylpyridine
  参考文献：
  名称：

  A stimuli-responsive orthogonal supramolecular polymer network formed by metal–ligand and host–guest interactions

  摘要：

  通过金属与配体之间的相互作用和主客体之间的相互作用的正交组合，构建了一种刺激响应型超分子聚合物网络。

  DOI：

  10.1039/c3cc47468b

文献信息

• A stimuli-responsive orthogonal supramolecular polymer network formed by metal–ligand and host–guest interactions
  作者：Jiayi Zhan、Qi Li、Qiuyue Hu、Qianqian Wu、Cunmin Li、Huayu Qiu、Mingming Zhang、Shouchun Yin

  DOI：10.1039/c3cc47468b

  日期：——

  A stimuli-responsive supramolecular polymer network was constructed by the orthogonal assembly of metal–ligand interactions and host–guest interactions.

  通过金属与配体之间的相互作用和主客体之间的相互作用的正交组合，构建了一种刺激响应型超分子聚合物网络。
• Photo-induced secondary assembly of bis(terpyridyl)dibenzo-24-crown-8/Zn2+ supramolecular polymer
  作者：Chao Xu、Yong Chen、Heng-Yi Zhang、Yu Liu

  DOI：10.1016/j.jphotochem.2015.04.014

  日期：2016.12

  A crown ether-based supramolecular gel with a three-dimensional network structure was successfully constructed via a hierarchical induced assembly strategy and characterized by UV/vis NMR, viscometry and DLS. Therein, the coordination linkage of bis(terpyridyl)dibenzo-24-crown-8 1 with Zn2+ produces the 1/Zn2+ supramolecular polymer as the primary assembly. Then, the anthryl-dibenzylammonium guest 2 was grafted to the 1/Zn2+ supramolecular polymer via the non-covalent association of dibenzylammonium moieties on guests with the dibenzo-24-crown-8 rings on supramolecular polymer. Furthermore, the supramolecular polymer with anthryl grafts underwent a photo-induced secondary assembly to produce the supramolecular gel, which could be reversibly disassembled by a thermoinduced dissociation of anthracene dimers. These photo/thermo-induced hierarchical assembly/disassembly behaviors will provide a potential way to construct degradable hierarchical supramolecular assemblies employing environment-friendly external stimuli, such as light and heat, as controlling method. (C) 2015 Elsevier B.V. All rights reserved.