| 174683-86-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 174683-86-4
• 化学式: C₁₈H₁₄N₂O₆Pd
• 分子量: 460.739
• InChiKey: SWQCMJHDVLGEIF-HCURTGQUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  gadolinium(III) nitrate hexahydrate 、 在 LiOH*H₂O 作用下， 以 甲醇 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Palladium(II)-Lanthanide(III) Complexes of a Dinucleating Ligand, N,N'-BIS(3-Carboxysalicylidene)ethylenediamine

  摘要：

  Heteronuclear palladium(II)-lanthanide(III) complexes of H(4)fsaen, PdLn(fsaen)(NO3)(H2O)(n) (Ln = La, Ce, Nd, Eu, Gd, Ho or Yb; n=4 for Ln=La, n=3.5 for Ln=Ce-Gd, n=3 for Ln=Ho, Yb), were synthesized and characterized based on elemental analyses, thermogravimetry, and IR spectral and magnetic susceptibility measurements, where H(4)fsaen denotes N,N'-bis(3-carboxysalicylidine)ethylenediamine. Palladium(II) and lanthanide(III) ions are located at the endogenous N2O2- and the exogenous O-4-coordination sites of the ligand, respectively. The respective magnetic moments at room temperature were within the range reported for the tervalent lanthanide compounds.

  DOI：

  10.1080/00945719608004243
• 作为产物：
  描述：

  bis(acetylacetonato)palladium(II) 、 N,N'-bis(3-carboxysalicylidene)ethylenediamine 在 (CH₃)3N 作用下， 以 二甲基亚砜 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Palladium(II)-Lanthanide(III) Complexes of a Dinucleating Ligand, N,N'-BIS(3-Carboxysalicylidene)ethylenediamine

  摘要：

  Heteronuclear palladium(II)-lanthanide(III) complexes of H(4)fsaen, PdLn(fsaen)(NO3)(H2O)(n) (Ln = La, Ce, Nd, Eu, Gd, Ho or Yb; n=4 for Ln=La, n=3.5 for Ln=Ce-Gd, n=3 for Ln=Ho, Yb), were synthesized and characterized based on elemental analyses, thermogravimetry, and IR spectral and magnetic susceptibility measurements, where H(4)fsaen denotes N,N'-bis(3-carboxysalicylidine)ethylenediamine. Palladium(II) and lanthanide(III) ions are located at the endogenous N2O2- and the exogenous O-4-coordination sites of the ligand, respectively. The respective magnetic moments at room temperature were within the range reported for the tervalent lanthanide compounds.

  DOI：

  10.1080/00945719608004243