DMJ-An-Ph5-NI | 1200040-30-7

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: DMJ-An-Ph5-NI
• 英文别名: 6-(2,5-Ditert-butylphenyl)-13-[4-[4-[4-[4-[4-[10-(6,8-dimethyl-1-azatricyclo[7.3.1.05,13]trideca-5,7,9(13)-trien-7-yl)anthracen-9-yl]phenyl]phenyl]phenyl]phenyl]phenyl]-6,13-diazatetracyclo[6.6.2.04,16.011,15]hexadeca-1(15),2,4(16),8,10-pentaene-5,7,12,14-tetrone；6-(2,5-ditert-butylphenyl)-13-[4-[4-[4-[4-[4-[10-(6,8-dimethyl-1-azatricyclo[7.3.1.05,13]trideca-5,7,9(13)-trien-7-yl)anthracen-9-yl]phenyl]phenyl]phenyl]phenyl]phenyl]-6,13-diazatetracyclo[6.6.2.04,16.011,15]hexadeca-1(15),2,4(16),8,10-pentaene-5,7,12,14-tetrone
• CAS: 1200040-30-7
• 化学式: C₈₆H₇₁N₃O₄
• 分子量: 1210.53
• InChiKey: UEUVISOTWOBULL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  21.5
• 重原子数：
  93
• 可旋转键数：
  10
• 环数：
  16.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  78
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  DMJ-An-Ph-I 、 在 四(三苯基膦)钯 作用下， 以 甲苯 为溶剂， 反应 12.0h， 生成 DMJ-An-Ph5-NI
  参考文献：
  名称：

  Spin-Selective Charge Transport Pathways through p-Oligophenylene-Linked Donor−Bridge−Acceptor Molecules

  摘要：

  A series of donor-bridge-acceptor (D-B-A) triads have been synthesized in which the donor, 3,5-dimethyl-4-(9-anthracenyl)julolidine (DMJ-An), and the acceptor, naphthalene-1,8:4,5-bis(dicarboximide) (NI), are linked by p-oligophenylene (Ph-n) bridging units (n = 1-5). Photoexcitation of DMJ-An produces DMJ(+center dot)-An(-center dot) quantitatively, so that An(-center dot) acts as a high potential electron donor, which rapidly transfers an electron to NI yielding a long-lived spin-coherent radical ion pair (DMJ(+center dot)-An-Ph-n-NI-center dot). The charge transfer properties of 1-5 have been studied using transient absorption spectroscopy, magnetic field effects (MFEs) on radical pair and triplet yields, and time-resolved electron paramagnetic resonance (TREPR) spectroscopy. The charge separation (CS) and recombination (CR) reactions exhibit exponential distance dependencies with damping coefficients of beta = 0.35 angstrom(-1) and 0.34 angstrom(-1), respectively. Based on these data, a change in mechanism from superexchange to hopping was not observed for either process in this system. However, the CR reaction is spin-selective and produces the singlet ground state and both (3)*An and (3)*NI. A kinetic analysis of the MFE data shows that superexchange dominates both pathways with beta = 0.48 angstrom(-1) for the singlet CR pathway and beta = 0.35 angstrom(-1) for the triplet CR pathway. MFEs and TREPR experiments were used to measure the spin-spin exchange interaction, 2J, which is directly related to the electronic coupling matrix element for CR, V-CR(2). The magnitude of 2J also shows an exponential distance dependence with a damping coefficient alpha = 0.36 angstrom(-1), which agrees with the P values obtained from the distance dependence for triplet CR. These results were analyzed in terms of the bridge molecular orbitals that participate in the charge transport mechanism.

  DOI：

  10.1021/ja907625k

文献信息

• Spin-Selective Charge Transport Pathways through <i>p-</i>Oligophenylene-Linked Donor−Bridge−Acceptor Molecules
  作者：Amy M. Scott、Tomoaki Miura、Annie Butler Ricks、Zachary E. X. Dance、Emilie M. Giacobbe、Michael T. Colvin、Michael R. Wasielewski

  DOI：10.1021/ja907625k

  日期：2009.12.9

  A series of donor-bridge-acceptor (D-B-A) triads have been synthesized in which the donor, 3,5-dimethyl-4-(9-anthracenyl)julolidine (DMJ-An), and the acceptor, naphthalene-1,8:4,5-bis(dicarboximide) (NI), are linked by p-oligophenylene (Ph-n) bridging units (n = 1-5). Photoexcitation of DMJ-An produces DMJ(+center dot)-An(-center dot) quantitatively, so that An(-center dot) acts as a high potential electron donor, which rapidly transfers an electron to NI yielding a long-lived spin-coherent radical ion pair (DMJ(+center dot)-An-Ph-n-NI-center dot). The charge transfer properties of 1-5 have been studied using transient absorption spectroscopy, magnetic field effects (MFEs) on radical pair and triplet yields, and time-resolved electron paramagnetic resonance (TREPR) spectroscopy. The charge separation (CS) and recombination (CR) reactions exhibit exponential distance dependencies with damping coefficients of beta = 0.35 angstrom(-1) and 0.34 angstrom(-1), respectively. Based on these data, a change in mechanism from superexchange to hopping was not observed for either process in this system. However, the CR reaction is spin-selective and produces the singlet ground state and both (3)*An and (3)*NI. A kinetic analysis of the MFE data shows that superexchange dominates both pathways with beta = 0.48 angstrom(-1) for the singlet CR pathway and beta = 0.35 angstrom(-1) for the triplet CR pathway. MFEs and TREPR experiments were used to measure the spin-spin exchange interaction, 2J, which is directly related to the electronic coupling matrix element for CR, V-CR(2). The magnitude of 2J also shows an exponential distance dependence with a damping coefficient alpha = 0.36 angstrom(-1), which agrees with the P values obtained from the distance dependence for triplet CR. These results were analyzed in terms of the bridge molecular orbitals that participate in the charge transport mechanism.