| 1574527-35-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1574527-35-7
• 化学式: C₂₁H₁₅ClN₂O₂Pd
• 分子量: 469.235
• InChiKey: LDFJPHCSVCYRMR-XSEMBQBTSA-L

反应信息

• 作为产物：
  描述：

  palladium diacetate 、 N,N'-bis(salicylidene)-2-chlorophenylmethanediamine 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  A simple and efficient tetradentate Schiff base derived palladium complex for Suzuki–Miyaura reaction in water

  摘要：

  A simple and efficient catalytic system based on Pd complex of tetradentate Schiff base ligands is found to be highly active (up to 99% isolated yield) for Suzuki-Miyaura reaction of aryl bromides with arylboronic acids in water at room temperature. Further the scope of this protocol has been extended to the Suzuki-Miyaura cross-coupling reaction of aryl chlorides with arylbronic acids in isopropanol. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.01.041
• 作为试剂：
  描述：

  对溴甲苯 、 4-叔丁基苯硼酸 在 C₂₁H₁₅ClN₂O₂Pd 、 potassium carbonate 作用下， 以 水 为溶剂， 反应 0.08h， 以98%的产率得到1-(4-tert-butylphenyl)-4-methylbenzene
  参考文献：
  名称：

  A simple and efficient tetradentate Schiff base derived palladium complex for Suzuki–Miyaura reaction in water

  摘要：

  A simple and efficient catalytic system based on Pd complex of tetradentate Schiff base ligands is found to be highly active (up to 99% isolated yield) for Suzuki-Miyaura reaction of aryl bromides with arylboronic acids in water at room temperature. Further the scope of this protocol has been extended to the Suzuki-Miyaura cross-coupling reaction of aryl chlorides with arylbronic acids in isopropanol. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.01.041