(2R,3S,7R)-7-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-3-ethoxy-3-methyl-8-oxo-5-thia-1-aza-bicyclo[4.2.0]octane-2-carboxylic acid methyl ester | 73816-18-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (2R,3S,7R)-7-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-3-ethoxy-3-methyl-8-oxo-5-thia-1-aza-bicyclo[4.2.0]octane-2-carboxylic acid methyl ester
• CAS: 73816-18-9
• 化学式: C₁₉H₂₀N₂O₆S
• 分子量: 404.444
• InChiKey: ZHSBKGUQXOPSLH-BWMJQDETSA-N

反应信息

• 作为产物：
  描述：

  (2S,3S,7R)-3-Chloro-7-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-3-methyl-8-oxo-5-thia-1-aza-bicyclo[4.2.0]octane-2-carboxylic acid methyl ester 在 乙醇 作用下， 生成 (6R)-3t-hydroxy-3c-methyl-8-oxo-7t-phthalimido-(6rH)-5-thia-1-aza-bicyclo[4.2.0]octane-2c-carboxylic acid methyl ester 、 (2R,3S,7R)-7-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-3-ethoxy-3-methyl-8-oxo-5-thia-1-aza-bicyclo[4.2.0]octane-2-carboxylic acid methyl ester
  参考文献：
  名称：

  Neighboring-group participation by sulfide sulfur in solvolytic interconversion between penam and cepham systems. A kinetic study on the solvolyses of 2'.alpha.- and 2'.beta.-halo-substituted-6-phthalimidopenam and 3.beta.-halo-substituted-7-phthalimidocepham methyl esters

  摘要：

  DOI：

  10.1021/jo01304a013