2-[2-(vinyloxy)phenyl]benzo[d]thiazole | 1312163-33-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: 2-[2-(vinyloxy)phenyl]benzo[d]thiazole
• 英文别名: 2-(2-Ethenoxyphenyl)-1,3-benzothiazole；2-(2-ethenoxyphenyl)-1,3-benzothiazole
• CAS: 1312163-33-9
• 化学式: C₁₅H₁₁NOS
• 分子量: 253.324
• InChiKey: MUWXRSTURXIMFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  50.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-(2-羟基苯基)苯并噻唑 在 potassium tert-butylate 、 potassium carbonate 作用下， 以 二甲基亚砜 、 N,N-二甲基甲酰胺 为溶剂， 反应 4.0h， 生成 2-[2-(vinyloxy)phenyl]benzo[d]thiazole
  参考文献：
  名称：

  A “Reactive” Ratiometric Fluorescent Probe for Mercury Species

  摘要：

  A ratiometric fluorescent probe for mercury species is developed bused on the metal-promoted hydrolysis of a vinyl ether derivative of 2-(benzothiazol-2-yl)phenol in a buffer solution. The probe responds selectively to mercury species over various other metal ions with a marked fluorescence change from blue to cyan through the excited state intramolecular proton transfer (ESIPT) process. The fluorescence titration is complete with 0.5 equiv of HgCl2, which indicates that the probe also responds to organomercury species, RHgCl.

  DOI：

  10.1021/ol2011693

文献信息

• ORGANIC METAL COMPLEX, LIGHT EMITTING MATERIAL, DELAYED FLUORESCENT MATERIAL, AND ORGANIC LIGHT EMITTING DEVICE
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US20160185765A1

  公开（公告）日：2016-06-30

  An organic metal complex represented by the following general formula is useful as a light emitting material for an organic electroluminescent device and others. X represents O, S or —N(R 7 )—; Y represents O, S or —N(—SO 2 —R 8 )—; R 1 to R 8 represent H, an alkyl group or an aryl group; at least one of Z 1 and Z 2 represents a phenoxazin-10-yl group, a phenothiazin-10-yl group, a phenazin-10-yl group, etc.; M represents an element of the group 1 except for hydrogen, the group 2, the group 11, the group 12, or the group 13 of the periodic table; L represents a ligand; n is 1 to 3; and m is 0 to 2:

  下列一般式所代表的有机金属配合物可用作有机电致发光器件和其他材料的发光材料。 X代表O、S或—N（R7）—；Y代表O、S或—N（—SO2—R8）—；R1至R8代表H、烷基或芳基；Z1和Z2中至少一个代表苯氧嗪-10-基团、苯并噻唑-10-基团、苯并氮杂菁-10-基团等；M代表周期表的1族除氢外的元素、2族、11族、12族或13族元素；L代表配体；n为1至3；m为0至2。
• US9957260B2
  申请人：——

  公开号：US9957260B2

  公开（公告）日：2018-05-01
• A “Reactive” Ratiometric Fluorescent Probe for Mercury Species
  作者：Mithun Santra、Basab Roy、Kyo Han Ahn

  DOI：10.1021/ol2011693

  日期：2011.7.1

  A ratiometric fluorescent probe for mercury species is developed bused on the metal-promoted hydrolysis of a vinyl ether derivative of 2-(benzothiazol-2-yl)phenol in a buffer solution. The probe responds selectively to mercury species over various other metal ions with a marked fluorescence change from blue to cyan through the excited state intramolecular proton transfer (ESIPT) process. The fluorescence titration is complete with 0.5 equiv of HgCl2, which indicates that the probe also responds to organomercury species, RHgCl.