2,6-(PhO)2C6H3SiMe3 | 1308886-95-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,6-(PhO)2C6H3SiMe3
• 英文别名: (2,6-Diphenoxyphenyl)-trimethylsilane；(2,6-diphenoxyphenyl)-trimethylsilane
• CAS: 1308886-95-4
• 化学式: C₂₁H₂₂O₂Si
• 分子量: 334.49
• InChiKey: LBGGQLVUYYGBCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.82
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  三甲基氯硅烷 、 2,6-(PhO)2C6H3Li 以 四氢呋喃 、 甲苯 为溶剂， 反应 72.0h， 以73%的产率得到2,6-(PhO)2C6H3SiMe3
  参考文献：
  名称：

  Synthesis and characterisation of complexes of the 2,6-diphenoxyphenyl ligand

  摘要：

  The use of the 2,6-diphenoxyphenyl ligand has facilitated the stabilisation of lithium, silane and stannane complexes. The ortho-metallation reaction between 1,3-(PhO)(2)C6H4 and (BuLi)-Bu-n yields 2,6-(PhO)(2)C6H3Li (1); the crystallographically characterised dimer [2,6-(PhO)(2)C6H3Li(OEt2)](2) ([1.Et2O](2)) can be obtained by the crystallisation of 1 from diethyl ether. The reaction between 1 and Me3ECl gives rise to the structurally authenticated complexes 2,6-(PhO)(2)C6H3EMe3 [E = Si, 2; E = Sn, 3]. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.12.023

文献信息

• Synthesis and characterisation of complexes of the 2,6-diphenoxyphenyl ligand
  作者：Alexander J. Blake、Alexandra L. Gower、William Lewis、Graeme J. Moxey、Thomas J. Reade、Deborah L. Kays

  DOI：10.1016/j.jorganchem.2010.12.023

  日期：2011.5

  The use of the 2,6-diphenoxyphenyl ligand has facilitated the stabilisation of lithium, silane and stannane complexes. The ortho-metallation reaction between 1,3-(PhO)(2)C6H4 and (BuLi)-Bu-n yields 2,6-(PhO)(2)C6H3Li (1); the crystallographically characterised dimer [2,6-(PhO)(2)C6H3Li(OEt2)](2) ([1.Et2O](2)) can be obtained by the crystallisation of 1 from diethyl ether. The reaction between 1 and Me3ECl gives rise to the structurally authenticated complexes 2,6-(PhO)(2)C6H3EMe3 [E = Si, 2; E = Sn, 3]. (C) 2011 Elsevier B.V. All rights reserved.