Tri(propan-2-yl)silyl 3-methoxybenzoate | 1322068-62-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Tri(propan-2-yl)silyl 3-methoxybenzoate
• 英文别名: tri(propan-2-yl)silyl 3-methoxybenzoate
• CAS: 1322068-62-1
• 化学式: C₁₇H₂₈O₃Si
• 分子量: 308.493
• InChiKey: RNWPBBQRFQYSOA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.03
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  triisopropylbromosilane 、 3-甲氧基苯甲酸 在 咪唑 、 4-二甲氨基吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 生成 Tri(propan-2-yl)silyl 3-methoxybenzoate
  参考文献：
  名称：

  A new and efficient method for the synthesis of bromosilanes from hydrosilanes using Br3CCOOEt/PdCl2 as the catalyst

  摘要：

  Bromosilanes were prepared conveniently and efficiently via the reaction of hydrosilanes and Br3CCOOEt in the presence of a catalytic amount of PdCl2 in refluxing THE over 15 min in high yields. The developed methodology was further applied for the one-pot synthesis of silyl ethers and silyl esters in excellent yields. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.03.028

文献信息

• A new and efficient method for the synthesis of bromosilanes from hydrosilanes using Br3CCOOEt/PdCl2 as the catalyst
  作者：Phatsupha Srithanakit、Warinthorn Chavasiri

  DOI：10.1016/j.tetlet.2011.03.028

  日期：2011.5

  Bromosilanes were prepared conveniently and efficiently via the reaction of hydrosilanes and Br3CCOOEt in the presence of a catalytic amount of PdCl2 in refluxing THE over 15 min in high yields. The developed methodology was further applied for the one-pot synthesis of silyl ethers and silyl esters in excellent yields. (C) 2011 Elsevier Ltd. All rights reserved.