4-(3-溴丙基)-2-[4-(3-溴丙基)吡啶-2-基]吡啶 | 191921-13-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 4-(3-溴丙基)-2-[4-(3-溴丙基)吡啶-2-基]吡啶
• 英文名称: 4,4'-Bis-(3-bromo-propyl)-[2,2']bipyridinyl
• 英文别名: 4,4'-Bis(3-bromopropyl)-2,2'-bipyridine；4-(3-bromopropyl)-2-[4-(3-bromopropyl)pyridin-2-yl]pyridine
• CAS: 191921-13-8
• 化学式: C₁₆H₁₈Br₂N₂
• 分子量: 398.14
• InChiKey: FQASHXSEOIKAFK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  20
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4,4'-di(lithiomethyl)-2,2'-bipyridine 、 4-(3-溴丙基)-2-[4-(3-溴丙基)吡啶-2-基]吡啶 以 四氢呋喃 为溶剂， 以5%的产率得到3,14,17,28-Tetrazapentacyclo[23.3.1.12,6.111,15.116,20]dotriaconta-1(28),2,4,6(32),11(31),12,14,16,18,20(30),25(29),26-dodecaene
  参考文献：
  名称：

  Bipyridine based exoditopic ligands: Synthesis and structural analysis of homobinuclear ruthenium complexes

  摘要：

  synthesis of new macrocyclic ligands based on 2,2'-bipyridine unites interconnected at the 4 and 4' positions by alkyl chains was achieved. Homobinuclear Ru-II complexes were formed and the solid state structure of one of the diastereoisomers was investigated by X-ray analysis. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)00757-0
• 作为产物：
  描述：

  4,4'-二甲基-2,2'-联吡啶 在 硫酸 、 oxonium 、 氢溴酸 、 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 生成 4-(3-溴丙基)-2-[4-(3-溴丙基)吡啶-2-基]吡啶
  参考文献：
  名称：

  Bipyridine based exoditopic ligands: Synthesis and structural analysis of homobinuclear ruthenium complexes

  摘要：

  synthesis of new macrocyclic ligands based on 2,2'-bipyridine unites interconnected at the 4 and 4' positions by alkyl chains was achieved. Homobinuclear Ru-II complexes were formed and the solid state structure of one of the diastereoisomers was investigated by X-ray analysis. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)00757-0

文献信息

• Bipyridine based exoditopic ligands: Synthesis and structural analysis of homobinuclear ruthenium complexes
  作者：Christian Kaes、Mir Wais Hosseini、André De Cian、Jean Fischer

  DOI：10.1016/s0040-4039(97)00757-0

  日期：1997.6

  synthesis of new macrocyclic ligands based on 2,2'-bipyridine unites interconnected at the 4 and 4' positions by alkyl chains was achieved. Homobinuclear Ru-II complexes were formed and the solid state structure of one of the diastereoisomers was investigated by X-ray analysis. (C) 1997 Elsevier Science Ltd.