| 101056-11-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 101056-11-5
• 化学式: C₃₂H₁₆FeN₈O
• 分子量: 584.379
• InChiKey: FFOHQMFQDDXVNQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [phthalocyaninatoiron(II)]2O2 以 solid matrix 为溶剂， 以0%的产率得到
  参考文献：
  名称：

  双氧基质中亚铁卟啉及相关化合物的共振拉曼光谱

  摘要：

  DOI：

  10.1021/j100400a007

文献信息

• Synthesis, Characterization and Dielectric Properties of Novel Metal Oxide - Phthalocyanine Nanocomposites
  作者：Alia Salama、amal abd el-karim

  DOI：10.21608/ejchem.2018.2563.1207

  日期：2018.4.1

  Organic and metal-organic polymers which have electrical properties have opened up a promising field in material science and engineering. Phthalocyanine (H2Pc) and metal oxide– phthalocyanine (MO-Pc) where (MO = ZnO, NiO, FeO and CoO) were prepared by urea fusion technique. The prepared composites were identified by means of Fourier transform infrared spectroscopy (IR) and X-ray diffraction (XRD). The XRD data indicate that the ZnO-Pc and NiO-Pc are highly crystalline and particle sizes are 13 nm and 9 nm respectively. The dielectric properties including dielectric constant ɛ' and dielectric loss ɛ'' of the prepared composites were calculated from the experimental capacitance values in the frequency range 100 Hz to 5MHz and in the temperature range of 25oC to 120oC. Generally, ɛ' are found to be decreased with increasing frequency and increase with increasing temperature. It is obvious that, appearance of peak for each MO in the dielectric loss suggests the presence of relaxing dipoles in the MO-Pc nanocomposites. The relaxation time τ, activation enthalpy ΔH and the entropy change ΔS of the prepared composites were calculated. The obtained data were correlated to the nature of doping metal oxide.

  具有电学性能的有机和金属有机聚合物开辟了材料科学和工程领域的一个有前途的方向。采用尿素熔融技术制备了酞菁（H2Pc）和金属氧化物-酞菁（MO-Pc），其中（MO = ZnO，NiO，FeO和CoO）。通过傅里叶变换红外光谱（IR）和X射线衍射（XRD）对制备的复合材料进行了鉴定。XRD数据表明，ZnO-Pc和NiO-Pc高度结晶，颗粒大小分别为13纳米和9纳米。通过频率范围为100 Hz至5 MHz和温度范围为25°C至120°C的实验电容值计算了制备复合材料的介电性能，包括介电常数ɛ'和介电损耗ɛ''。一般来说，随着频率的增加，ɛ'被发现减少，而随着温度的升高则增加。显然，每个MO在介电损耗中出现峰值，表明MO-Pc纳米复合材料中存在弛豫偶极子。计算了制备复合材料的弛豫时间τ、活化焓ΔH和熵变ΔS。得到的数据与掺杂金属氧化物的性质相关联。