PtI2(4,5-di(hydroseleno)-1,3-diselenole-2-selenate)(N-ethyl-2-methylpyridine-2-carbaldimine) | 136901-33-2

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: PtI2(4,5-di(hydroseleno)-1,3-diselenole-2-selenate)(N-ethyl-2-methylpyridine-2-carbaldimine)
• CAS: 136901-33-2
• 化学式: C₁₁H₁₀I₂N₂PtSe₅
• 分子量: 1013.9
• InChiKey: YOUYQECUINAZCY-NOJKJMGTSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-ethyl-2-methylpyridine-2-carbaldimine dichloro platinum 在 Na 、 I₂ 作用下， 以 甲醇 、 二甲基亚砜 、 N,N-二甲基甲酰胺 为溶剂， 生成 PtI2(4,5-di(hydroseleno)-1,3-diselenole-2-selenate)(N-ethyl-2-methylpyridine-2-carbaldimine)
  参考文献：
  名称：

  Preparations and spectroscopic properties of Pt(C3Se5)(N2-chelate) and its oxidized complexes

  摘要：

  Pt(C3Se5)(L) [C3Se5(2-) = 4,5-di(hydroseleno)-1,3-diselenole-2-selenate; L = N-alkyl-2-methylpyridine-2-carbaldimine (alkyl = ethyl and i-propyl) and 2,2'-bipyridine] have been prepared. They are polarized, exhibiting an intramolecular ligand-to-ligand charge-transfer absorption band around 16 000 cm-1. The Pt-Se bond order of the Pt(C3Se5)(L) complexes is somewhat higher than the Pt-S bond order of Pt(C3S5)(L). Oxidation of these complexes by iodine has afforded the complexes with the Pt-I bond, behaving as semiconductors with electrical conductivities of 1 X (10(-6)-10(-7))S cm-1 measured for compacted pellets at room temperature. Electronic absorption, H-1 NMR, and IR spectroscopies of the complexes as well as their electrochemical properties are described.

  DOI：

  10.1016/s0020-1693(00)83011-x