3-methoxy-2-methyl-acrylic acid ethyl ester | 98962-54-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 乙烯酯类
• 英文名称: 3-methoxy-2-methyl-acrylic acid ethyl ester
• 英文别名: 3-Methoxy-2-methyl-acrylsaeure-aethylester；ethyl (E)-3-methoxy-2-methylprop-2-enoate
• CAS: 98962-54-0
• 化学式: C₇H₁₂O₃
• 分子量: 144.17
• InChiKey: IFPLIOCMNUUFHO-AATRIKPKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-Aethoxymethoxymethyl-propionsaeure-aethylester 在 硫酸 、 对甲苯磺酸 作用下， 180.0 ℃ 、4.0 kPa 条件下， 生成 3-methoxy-2-methyl-acrylic acid ethyl ester
  参考文献：
  名称：

  Takamizawa et al., Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1959, vol. 79, p. 664,668

  摘要：

  DOI：

文献信息

• Internally coordinated organoboranes
  申请人：Lord Corporation

  公开号：US20040242817A1

  公开（公告）日：2004-12-02

  Disclosed are internally coordinated organoboranes as 5, 6, or 7-membered rings formed from an unsaturated amine, amidine, or guanidine and dialkylhydroborane under hydroboration conditions, as well as two-part adhesive or coating kits containing radical polymerizable material and the internally coordinated organoborane. A representative internally coordinated organoborane is: 1

  本发明涉及在氢化硼条件下，从不饱和胺、酰胺或脲和二烷基氢硼烷形成的5、6或7元环的内部配位有机硼化合物，以及包含自由基聚合材料和内部配位有机硼烷的两部分粘合剂或涂料套件。代表性的内部配位有机硼化合物为：1。
• Polymers for antifouling coatings and a process for the preparation thereof
  申请人：Jotun A/S

  公开号：US20030225230A1

  公开（公告）日：2003-12-04

  Polymer for antifouling coatings which comprises units corresponding to the following monomers: A) 5 to 100 mol. % of one or more compounds of general formula (I) in which R=H or CH 3 ; X=O or S; R 1 =Ph(R 2 ) m , —C(H) 3−(p+q) (CO—R) 3 p (COOR 3 ) q , —(CH 2 ) n −(CO) t —COOR 3 or optionally substituted thiadiazolyl and thiazolylsulfamyl groups; Ph=phenyl; m=1-3; p=0-3; q=0-3; p+q=1-3; s=0 or 1; t=0 or 1; R 2 =each independently selected from halogen, —C(O)H, —COOR 3 , —CH 2 —COOR 3 , —O—R 3 , —NH COOR 3 , —NH—CO—R 3 and —NH 2 ; R 3 =II or optionally halogen substituted alkyl, aryl, cycloalkyl, aralkyl groups with 1-10 C atoms; and B) 0 to 95 mol. % of one or more other ethylenically unsaturated compound. Processes for preparing the polymers defined above, points containing said polymers, and the use of monomers of the above formula (I) for preparing for antifouling coatings. 1

  抗污涂层聚合物，其包含与以下单体相应的单位：A）5至100摩尔％的一个或多个化合物，其通式为（I），其中R= H或CH3; X= O或S; R1= Ph（R2）m，-C（H）3−（p+q）（CO-R）3p（COOR3）q，-（CH2）n−（CO）t-COOR3或可选的取代硫脲基和噻唑磺酰基；Ph=苯基；m=1-3；p=0-3；q=0-3；p+q=1-3；s=0或1；t=0或1；R2=各自独立选择自卤素，-C（O）H，-COOR3，- -COOR3，-O-R3，-NH COOR3，-NH-CO-R3和-NH2; R3=II或可选的卤素取代的烷基，芳基，环烷基，芳基烷基，具有1-10个C原子；和B）0至95摩尔％的一个或多个其他乙烯基不饱和化合物。制备上述聚合物的过程，包含该聚合物的点，以及上述式（I）的单体用于制备抗污涂层的使用。
• NOVEL GLYCOSYL HYDROLASE WITH BETA-XYLOSIDASE AND BETA-GLUCOSIDASE ACTIVITIES AND USES THEREOF
  申请人：Zhu Ping

  公开号：US20130130330A1

  公开（公告）日：2013-05-23

  A novel glycosyl hydrolase with activities of beta-xylosidase and beta-glucosidase is provided. Said glycosyl hydrolase can convert 7-xylosyltaxane compounds to 7-hydroxyltaxane compounds.

  提供了一种新型的糖基水解酶，具有β-木糖苷酶和β-葡萄糖苷酶的活性。该糖基水解酶可以将7-木糖基紫杉烷类化合物转化为7-羟基紫杉烷类化合物。
• A solid entrapped emollient-moisturizer composition and the use thereof
  申请人：Wickhen Products, Inc.

  公开号：EP0061701A2

  公开（公告）日：1982-10-06

  This invention relates to solid, entrapped emollient-moisturizer compositions comprising a crosslinked polymer matrix and an emollient-moisturizer. The invention provides for conversion of solid and/or liquid emollients or moisturizers into solid, free-flowing forms by entrapment of the functional materials in a hydrophobic polymer lattice.

  本发明涉及固态夹带润肤保湿组合物，该组合物由交联聚合物基质和润肤保湿剂组成。 本发明通过将功能材料夹带在疏水性聚合物晶格中，将固态和/或液态润肤剂或保湿剂转化为固态自由流动形式。
• Lattice-entrapped composition
  申请人：DOW CORNING CORPORATION

  公开号：EP0252463A2

  公开（公告）日：1988-01-13

  This invention relates to solid compositions wherein a non-cosmetic functional material is entrapped in the lattice of the cross-linked polymer during in situ polymerization of the monomers forming the polymer lattice. The invention provides for conversion of solid and/or liquid products into solid, free-flowing forms by entrapment of the functional materials in a hydrophobic polymer lattice.

  本发明涉及固体组合物，在形成聚合物晶格的单体原位聚合过程中，非化妆品功能材料被夹持在交联聚合物的晶格中。本发明通过在疏水性聚合物晶格中夹带功能材料，将固态和/或液态产品转化为固态的自由流动形式。