| 1616785-11-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 1616785-11-5
• 化学式: C₆H₅N₉O₄*H₂O*Mn
• 分子量: 340.117
• InChiKey: GGLJOUXNPGJKAD-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 以 甲醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Syntheses, structures and properties of five coordinating metallic complexes with the new carboxylate-bis(tetrazolyl)amine ligand

  摘要：

  Five new coordination compounds based on edtza or (datza)(2) ligands [edtza = ethyl-[N2(N3), N2 '-di(tetrazol-5-yl) amine] acetate and (datza)(2) = [di(tetrazol-5-yl)] amine-N2(N3), N2 '-diacetato anion] [Scheme 1], namely, binuclear cluster [Cd-2(edtza)(4)(H2O)(2)]center dot 2H(2)O (1) and 2-D polymers, [Ca(datza)(H-2 O)]center dot 2H(2)O (2), [M(datza)(H2O)] [M = Co (3), Mn (4)] and [Sr(datza)(H2O)] (5) have been successfully synthesized. They were characterized by elemental analysis, IR and single crystal X-ray diffraction analysis. The different crystal structures were controlled by not only the different coordinating and bridging modes of the edtza or (datza)(2) ligands but also simultaneously the formation of complementary intermolecular hydrogen bonds. Furthermore, the luminescence properties of 1-5 were investigated at room temperature in the solid state. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2014.04.013