| 154193-99-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 154193-99-4
• 化学式: C₁₈H₁₅AsI*GaI₄
• 分子量: 1010.48
• InChiKey: CCECFWHDIVBJPC-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  6.25
• 重原子数：
  25.0
• 可旋转键数：
  3.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  Triiodogallane;triphenylarsane 以 乙醚 为溶剂， 生成
  参考文献：
  名称：

  The preparation and structures of Ph3AsGaI3 and [Ph3AsI][GaI4]

  摘要：

  Colourless crystals of Ph(3)AsGaI(3) (1) have been prepared by reaction of triphenylarsine with GaI3.OEt(2) in diethyl ether. The structure of 1, in which the length of the As-Ga donor-acceptor bond is 2.490(2) Angstrom, has been determined by an X-ray diffraction study. In contact with the solvent phase, 1 is transformed into yellow crystals of [Ph(3)AsI][GaI4], 2 which has been structurally characterised by Raman Spectroscopy (As-I stretching at 196 cm(-1)) and by X-ray diffraction. The salt 2 is the first arsenic(V) iodo complex to have been examined crystallographically; the As-I bond distance is 2.485(1) Angstrom.

  DOI：

  10.1016/0022-328x(94)87020-9