methyl 2-(4-cyanophenyl)acrylate | 1350661-74-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methyl 2-(4-cyanophenyl)acrylate
• 英文别名: Methyl 2-(4-cyanophenyl)prop-2-enoate；methyl 2-(4-cyanophenyl)prop-2-enoate
• CAS: 1350661-74-3
• 化学式: C₁₁H₉NO₂
• 分子量: 187.198
• InChiKey: LJKKWNOYGYWPSR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  50.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  对氰基苯乙酮 在 氧气 、 亚甲兰 、 N,N-二异丙基乙胺 、 对甲苯磺酰氯 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 生成 methyl 2-(4-cyanophenyl)acrylate
  参考文献：
  名称：

  通过Wittig反应/单氧烯反应由芳基甲基酮合成2-芳基丙烯酸酯

  摘要：

  已经开发了一种有效的合成方法，用于通过Wittig反应和单线态氧烯反应从相应的芳基甲基酮合成2-芳基丙烯酸酯。在碱性条件下，与（甲氧基甲基）三苯基氯化在Wittig上与芳基甲基酮反应，得到甲基烯醇醚，然后通过单线态氧烯反应得到2-芳基丙烯酸酯，然后甲苯磺酸化并在一锅中消除为甲基烯醇醚。良品率高。

  DOI：

  10.1016/j.tetlet.2011.09.127

文献信息

• Novel multi-dentate phosphines for Pd-catalyzed alkoxycarbonylation of alkynes promoted by H2O additive
  作者：Da Yang、Lei Liu、Dong-Liang Wang、Yong Lu、Xiao-Li Zhao、Ye Liu

  DOI：10.1016/j.jcat.2019.01.031

  日期：2019.3

  A series of novel multi (bi-/tri-/tetra-)-dentate phosphines with good robustness against water and oxygen were synthesized and fully characterized. It was found that the developed ionic tri-dentate phosphine (L2′) enabled Pd-catalyzed alkoxycarbonylation of alkynes most efficiently while H2O was used as an additive instead of acid. As for L2′, its unique steric configuration with two types of potential

  合成并充分表征了一系列新颖的多（双-/三-/四-）齿状膦，其对水和氧具有良好的耐受性。发现开发的离子型三齿膦（L2'）能够最有效地Pd催化炔烃的烷氧基羰基化，同时使用H 2 O代替酸作为添加剂。至于L2'，其独特的空间构型以及两种潜在的PP螯合模式（P⋯P距离分别为4.31Å和4.36Å）到Pd中心使得相应的Pd催化剂具有高活性和良好的炔烃羰基羰基化稳定性。的原位FT-IR分析也证实了钯-H活性物质的形成和稳定性大大用的存在促进L2'和H 2 O添加剂。此外，作为离子化膦，固定在[Bmim] NTf 2的RTIL中的基于L2'的PdCl 2（MeCN）2系统可以循环使用7次，而不会造成明显的活性损失或金属浸出。
• Divergent Functionalization of Styrenes via Radical/Polar Crossover with CO ₂ and Sodium Sulfinates
  作者：Kimberly Benedetti Vega、José Antonio Campos Delgado、Lucas V. B. L. Pugnal、Burkhard König、José Tiago Menezes Correia、Márcio Weber Paixão

  DOI：10.1002/chem.202203625

  日期：——

  tunable multicomponent reaction which involves CO2, sodium sulfinates and styrenes to access both β-sulfonylateds carboxylic acids through radical–polar crossover process and to α-substituted acrylates through sequential sulfonyl radical addition/coupling/elimination process. This setup exhibits excellent tolerance to different functional groups and its application towards biologically relevant molecules

  不那么激进：自由基化学与极性化学的结合用于开发可调谐的多组分反应，该反应涉及 CO 2、亚磺酸钠和苯乙烯，通过自由基-极性交叉过程获得 β-磺酰化羧酸，并通过 α-取代丙烯酸酯连续的磺酰基加成/偶联/消除过程。该设置对不同的官能团表现出极好的耐受性，其在生物学相关分子和产品多样化方面的应用有助于该方法的综合效用。
• Solid electrolyte composition, solid electrolyte-containing sheet, all-solid state secondary battery, and methods for manufacturing solid electrolyte composition, solid electrolyte-containing sheet, all-solid state secondary battery
  申请人：FUJIFILM Corporation

  公开号：US10833351B2

  公开（公告）日：2020-11-10

  Provided are a solid electrolyte composition containing an inorganic solid electrolyte having a conductivity for ions of metals belonging to Group I or II of the periodic table and a compound having an anionic polymerizable functional group, a solid electrolyte-containing sheet containing an inorganic solid electrolyte having a conductivity for ions of metals belonging to Group I or II of the periodic table and an anionic polymer which bonds to the inorganic solid electrolyte, and an all-solid state secondary battery, and methods for manufacturing the solid electrolyte composition, the solid electrolyte-containing sheet, and the all-solid state secondary battery.

  本发明提供了一种固体电解质组合物，该组合物含有对属于元素周期表第 I 组或第 II 组的金属离子具有导电性的无机固体电解质和具有阴离子可聚合官能团的化合物、一种含固体电解质的薄片，其中含有对属于元素周期表第I或第II族的金属离子具有导电性的无机固体电解质和一种与无机固体电解质结合的阴离子聚合物，以及一种全固态二次电池，以及制造该固体电解质组合物、含固体电解质的薄片和全固态二次电池的方法。
• SOLID ELECTROLYTE COMPOSITION, SOLID ELECTROLYTE-CONTAINING SHEET, ALL-SOLID STATE SECONDARY BATTERY, AND METHODS FOR MANUFACTURING SOLID ELECTROLYTE COMPOSITION, SOLID ELECTROLYTE-CONTAINING SHEET, ALL-SOLID STATE SECONDARY BATTERY
  申请人：FUJIFILM Corporation

  公开号：US20190006700A1

  公开（公告）日：2019-01-03

  Provided are a solid electrolyte composition containing an inorganic solid electrolyte having a conductivity for ions of metals belonging to Group I or II of the periodic table and a compound having an anionic polymerizable functional group, a solid electrolyte-containing sheet containing an inorganic solid electrolyte having a conductivity for ions of metals belonging to Group I or II of the periodic table and an anionic polymer which bonds to the inorganic solid electrolyte, and an all-solid state secondary battery, and methods for manufacturing the solid electrolyte composition, the solid electrolyte-containing sheet, and the all-solid state secondary battery.
• Synthesis of 2-arylacrylic esters from aryl methyl ketones via Wittig reaction/singlet oxygen ene reaction
  作者：Sangjoon Park、Dongsik Yang、Kyoung Tae Kim、Heung Bae Jeon

  DOI：10.1016/j.tetlet.2011.09.127

  日期：2011.12

  has been developed for the synthesis of 2-arylacrylic esters from the corresponding aryl methyl ketones via Wittig reaction and singlet oxygen ene reaction. Wittig reaction to aryl methyl ketones with (methoxymethyl)triphenylphosphonium chloride in basic condition afforded the methyl enol ethers, and then 2-arylacrylic esters were obtained by singlet oxygen ene reaction, followed by tosylation and

  已经开发了一种有效的合成方法，用于通过Wittig反应和单线态氧烯反应从相应的芳基甲基酮合成2-芳基丙烯酸酯。在碱性条件下，与（甲氧基甲基）三苯基氯化在Wittig上与芳基甲基酮反应，得到甲基烯醇醚，然后通过单线态氧烯反应得到2-芳基丙烯酸酯，然后甲苯磺酸化并在一锅中消除为甲基烯醇醚。良品率高。